A comparison of argon and mixed gas plasmas for inductively coupled plasma-mass spectrometry
作者： J.W.H. Lam , G. Horlick
DOI: 10.1016/0584-8547(90)80185-L
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摘要: Abstract The effects of adding N 2 to the outer gas flow an Ar plasma in inductively coupled mass spectrometry (ICP-MS) are illustrated. With 5% added and provided central (nebulizer) is increased, modest signal enhancements (up a factor 4) observed. degree enhancement depends on extent which element forms strong metal oxide bond also, some extent, ionization potential. An important feature mixed plasmas for ICP-MS that signals analyte species (MO + ) certain background (ArO , ArOH ClO ArCl significantly reduced (an order magnitude) by addition flow. In these observations, results also presented O air (outer gas) (central plasmas.
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sci-hub.se 参考文章(12)
Robert S. Houk, Akbar Montaser, Velmer A. Fassel, Mass Spectra and Ionization Temperatures in an Argon-Nitrogen Inductively Coupled Plasma Applied Spectroscopy. ,vol. 37, pp. 425- 428 ,(1983) , 10.1366/0003702834634848
Akbar. Montaser, Shi Kit. Chan, David W. Koppenaal, Inductively coupled helium plasma as an ion source for mass spectrometry Analytical Chemistry. ,vol. 59, pp. 1240- 1242 ,(1987) , 10.1021/AC00135A038
G. W. Rice, A. P. D'Silva, V. A. Fassel, Analytically Useful Spectra Excited in an Atmospheric Pressure Active Nitrogen Afterglow Applied Spectroscopy. ,vol. 38, pp. 149- 154 ,(1984) , 10.1366/0003702844554288
Izumi Ishii, D. W. Golightly, Akbar Montaser, Radial excitation temperatures in argon-nitrogen inductively coupled plasmas Journal of Analytical Atomic Spectrometry. ,vol. 3, pp. 965- 968 ,(1988) , 10.1039/JA9880300965
E. Hywel Evans, Les Ebdon, Simple approach to reducing polyatomic ion interferences on arsenic and selenium in inductively coupled plasma mass spectrometry Journal of Analytical Atomic Spectrometry. ,vol. 4, pp. 299- 300 ,(1989) , 10.1039/JA9890400299
Margaret-Anne Vaughan, Gary Horlick, Samantha H. Tan, Effect of operating parameters on analyte signals in inductively coupled plasma mass spectrometry Journal of Analytical Atomic Spectrometry. ,vol. 2, pp. 765- 772 ,(1987) , 10.1039/JA9870200765
E.H. Choot, G. Horlic, Vertical spatial emission profiles in Ar-N2 mixed gas inductively coupled plasmas—I Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 41, pp. 889- 906 ,(1986) , 10.1016/0584-8547(86)80094-5
Douglas Hausler, Trace element analysis of organic solutions using inductively coupled plasma-mass spectrometry Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 42, pp. 63- 73 ,(1987) , 10.1016/0584-8547(87)80050-2
J.W.H. Lam, G. Horlick, Effects of sampler-skimmer separation in inductively coupled plasma-mass spectrometry Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 45, pp. 1327- 1338 ,(1990) , 10.1016/0584-8547(90)80186-M
Naoki Furuta, Spatial emission distribution of YO, Y I, Y II and Y III radiation in an inductively coupled plasma for the elucidation of excitation mechanisms Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 41, pp. 1115- 1129 ,(1986) , 10.1016/0584-8547(86)80130-6