Rates of Ionic Reactions in Aqueous Solutions

作者: A. R. Olson , T. R. Simonson

DOI: 10.1063/1.1747137

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摘要: The effect of the addition ``inert'' salts on ionic reaction rates is discussed. For reactions between ions same charge sign, caused almost exclusively by concentration and character salt sign opposite to that reactants. rate not dependent upon strength solutions. In both may affect rate, but one type be dominant. effects are quantitatively interpretable in terms an ion association constant specific constants for associated non‐associated further introduction activity coefficients necessary. which Livingston Diagram based have been explored from this viewpoint found quantitative accord.

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