NMR Studies of Elementary Steps of Multiple Proton and Deuteron Transfers in Liquids, Crystals, and Organic Glasses
作者： H.-H. Limbach
DOI: 10.1007/978-3-642-76260-4_11
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摘要: Dynamic high-resolution NMR spectroscopy of liquids and solids constitutes a convenient way to study kinetic hydrogen/deuterium isotope solid-state effects on multiple proton transfer reactions in different environments. In the case intramolecular double reactions, evidence for stepwise reaction pathways is obtained; each step only one jumps, whereas other remains bound. By contrast, intermolecular behave way. Here, both protons are flight rate-determining step. The origin behavior types discussed.
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