On the entropy of mixing of a binary mixture of hard spheres
作者： A. Meroni , A. Pimpinelli , L. Reatto
DOI: 10.1063/1.452961
关键词:
摘要: The entropy of mixing a binary mixture hard spheres at constant pressure is computed as function the diameter ratio on basis Mansoori–Carnahan–Starling equation state. Flory–Huggins form for poor approximation and becomes worse increasing values ratio. ideal gas closer to sphere result.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(11)
Peter A. Monson, Maurice Rigby, Mixtures of hard spherocylinders and hard spheres Molecular Physics. ,vol. 39, pp. 977- 988 ,(1980) , 10.1080/00268978000100831
J. H. Hildebrand, The Entropy of Solution of Molecules of Different Size The Journal of Chemical Physics. ,vol. 15, pp. 225- 228 ,(1947) , 10.1063/1.1746484
Raymond E. Goldstein, Model for phase equilibria in micellar solutions of nonionic surfactants Journal of Chemical Physics. ,vol. 84, pp. 3367- 3378 ,(1986) , 10.1063/1.450272
George M. Thurston, Daniel Blankschtein, Michael R. Fisch, George B. Benedek, Theory of thermodynamic properties and phase separation of micellar solutions with lower consolute points Journal of Chemical Physics. ,vol. 84, pp. 4558- 4562 ,(1986) , 10.1063/1.450028
George Jackson, John S. Rowlinson, Christine A. Leng, Phase equilibria in model mixtures of spherical molecules of different sizes Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 82, pp. 3461- 3473 ,(1986) , 10.1039/F19868203461
B. J. Alder, Studies in Molecular Dynamics. III. A Mixture of Hard Spheres The Journal of Chemical Physics. ,vol. 40, pp. 2724- 2730 ,(1964) , 10.1063/1.1725587
Paul J. Flory, Fifteenth Spiers Memorial Lecture. Thermodynamics of polymer solutions Discussions of the Faraday Society. ,vol. 49, pp. 7- 29 ,(1970) , 10.1039/DF9704900007
Pascal H. Fries, Jean-Pierre Hansen, A Monte Carlo study of semi-dilute hard sphere mixtures Molecular Physics. ,vol. 48, pp. 891- 901 ,(1983) , 10.1080/00268978300100641
J. J. Salacuse, G. Stell, Polydisperse systems: Statistical thermodynamics, with applications to several models including hard and permeable spheres The Journal of Chemical Physics. ,vol. 77, pp. 3714- 3725 ,(1982) , 10.1063/1.444274
Roland Kjellander, Phase separation of non-ionic surfactant solutions. A treatment of the micellar interaction and form Journal of the Chemical Society, Faraday Transactions. ,vol. 78, pp. 2025- 2042 ,(1982) , 10.1039/F29827802025