Reaction of transition metal carbonyls with heterocyclic systems: V. The reaction of Fe2(CO)9 with bicyclic 1,2-oxazine compounds
作者： Y. Becker , A. Eisenstadt , Y. Shvo
DOI: 10.1016/S0022-328X(00)90422-4
关键词:
摘要: Abstract A study of the reactions Fe 2 (CO) 9 towards bond has extended 9-phenyl-9-aza-8-oxabicyclo[3.2.2.]nona-6-ene (I) and 8-phenyl-9-aza-7-oxabicyclo[4.2.1]nona-2,4-diene (II). The are complete after 1 h at 40–50°C. Apart from corresponding anilino alcohols, products lack oxygen atom bond. stereochemistry is indicative an intramolecular process. Mechanistic proposals based on initial oxidative insertion iron into bond, followed by several competing reactions.
elsevier.com
sci-hub.se 参考文章(11)
Y. Becker, A. Eisenstadt, Y. Shvo, Reaction of transition metal carbonyls with heterocyclic systems—II : Diironnonarcarbonyl and 1,2-oxazines Tetrahedron. ,vol. 30, pp. 839- 847 ,(1974) , 10.1016/S0040-4020(01)97145-5
Y. Becker, A. Eisenstadt, Y. Shvo, Reaction of transition metal carbonyls with heterocyclic systems—III: SN2′-type reaction of complexed π-allyl systems Tetrahedron. ,vol. 32, pp. 2123- 2126 ,(1976) , 10.1016/0040-4020(76)85121-6
Rudolf Aumann, Klaus Fröhlich, Horst Ring, Lactones and Lactams by Light‐Induced Reaction of 2‐Vinyloxiranes and 2‐Vinylaziridines with Pentacarbonyliron—Insertion of Carbon Monoxide into an Iron‐Nitrogen σ Bond Angewandte Chemie. ,vol. 13, pp. 275- 276 ,(1974) , 10.1002/ANIE.197402751
O. L. Chapman, D. J. Pasto, A. A. Griswold, 1,8-Additions to Troponoid Systems: A Novel Route to Substituted Cycloheptadienes Journal of the American Chemical Society. ,vol. 84, pp. 1213- 1219 ,(1962) , 10.1021/JA00866A029
Thomas H. Whitesides, James P. Neilan, Mechanism of 1,5-hydrogen migration in diene iron carbonyl complexes Journal of the American Chemical Society. ,vol. 95, pp. 5811- 5813 ,(1973) , 10.1021/JA00798A089
Y. Becker, A. Eisenstadt, Y. Shvo, Reaction of transition metal carbonyl with heterocyclic systems I. Tetrahedron Letters. ,vol. 13, pp. 3183- 3186 ,(1978) , 10.1016/S0040-4039(01)93998-X
M. A. Hashmi, J. D. Munro, P. L. Pauson, J. M. Williamson, Metal derivatives of conjugated dienes. Part III. Some cyclohexa- and cyclohepta-dienyliron compounds Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 240- 243 ,(1967) , 10.1039/J19670000240
Youval Shvo, Eli Hazum, A simple method for the disengagement of organic ligands from iron complexes Journal of the Chemical Society, Chemical Communications. pp. 336- 337 ,(1974) , 10.1039/C39740000336
Frank D. Mango, Molecular Orbital Symmetry Conservation in Transition Metal Catalysis Advances in Catalysis. ,vol. 20, pp. 291- 325 ,(1969) , 10.1016/S0360-0564(08)60274-6
G. Kresze, G. Schulz, Additionsreaktionen der nitrosogruppe—II Tetrahedron. ,vol. 12, pp. 7- 12 ,(1961) , 10.1016/0040-4020(61)80093-8