Recent advances in catalysts for methanol synthesis via hydrogenation of CO and CO2
作者： Xin-Mei Liu , GQ Lu , Zi-Feng Yan , Jorge Beltramini , None
DOI: 10.1021/IE020979S
关键词:
摘要: Since the start of last century, methanol synthesis has attracted great interests because its importance in chemical industries and potential as an environmentally friendly energy carrier. The catalyst for been a key area research order to optimize reaction process. In literature, nature active site effects promoter support have extensively investigated. this updated review, recent progresses innovation, optimization conditions, mechanism, performance are comprehensively discussed. Key issues improvement highlighted, areas priority R&D identified conclusions.
acs.org
uq.edu.au
core.ac.uk参考文章(86)
John B. Bulko, Richard G. Herman, Kamil. Klier, Gary W. Simmons, Optical properties and electronic interactions of microcrystalline copper/zinc oxide (Cu/ZnO) catalysts The Journal of Physical Chemistry. ,vol. 83, pp. 3118- 3122 ,(1979) , 10.1021/J100487A011
A. Henrion, H. Ewald, H. Miessner, T. Zimmermann, Application of chemometric tools to catalysis : carbon monoxide hydrogenation on a multipromoted Rh/SiO2 catalyst Applied Catalysis. ,vol. 62, pp. 23- 34 ,(1990) , 10.1016/S0166-9834(00)82234-4
Jingang Wu, Shengcheng Luo, Jamil Toyir, Masahiro Saito, Masasmi Takeuchi, Taiki Watanabe, Optimization of preparation conditions and improvement of stability of Cu/ZnO-based multicomponent catalysts for methanol synthesis from CO2 and H2 Catalysis Today. ,vol. 45, pp. 215- 220 ,(1998) , 10.1016/S0920-5861(98)00218-1
R HERMAN, Catalytic synthesis of methanol from COH2: I. Phase composition, electronic properties, and activities of the Cu/ZnO/M2O3 catalysts Journal of Catalysis. ,vol. 56, pp. 407- 429 ,(1979) , 10.1016/0021-9517(79)90132-5
M.S. Spencer, Role of ZnO in methanol synthesis on copper catalysts Catalysis Letters. ,vol. 50, pp. 37- 40 ,(1998) , 10.1023/A:1019098414820
Yan Ma, Qi Sun, Dong Wu, Wen-Hao Fan, Yu-Long Zhang, Jing-Fa Deng, A practical approach for the preparation of high activity Cu/ZnO/ZrO2 catalyst for methanol synthesis from CO2 hydrogenation Applied Catalysis A-general. ,vol. 171, pp. 45- 55 ,(1998) , 10.1016/S0926-860X(98)00079-9
N JACKSON, Isotope studies of the effect of acid sites on the reactions of C3 intermediates during isosynthesis over zirconium dioxide and modified zirconium dioxide Journal of Catalysis. ,vol. 126, pp. 46- 56 ,(1990) , 10.1016/0021-9517(90)90045-L
M Bowker, RA Hadden, H Houghton, JNK Hyland, KC Waugh, The mechanism of methanol synthesis on copper/zinc oxide/alumina catalysts Journal of Catalysis. ,vol. 109, pp. 263- 273 ,(1988) , 10.1016/0021-9517(88)90209-6
Jamil Toyir, Pilar Ramı́rez de la Piscina, José Luis G Fierro, Narcı́s Homs, Catalytic performance for CO2 conversion to methanol of gallium-promoted copper-based catalysts: influence of metallic precursors Applied Catalysis B-environmental. ,vol. 34, pp. 255- 266 ,(2001) , 10.1016/S0926-3373(01)00203-X
Qi Sun, Yu-Long Zhang, Hai-Ying Chen, Jing-Fa Deng, Dong Wu, Song-Ying Chen, A Novel Process for the Preparation of Cu/ZnO and Cu/ZnO/Al2O3Ultrafine Catalyst: Structure, Surface Properties, and Activity for Methanol Synthesis from CO2+H2☆ Journal of Catalysis. ,vol. 167, pp. 92- 105 ,(1997) , 10.1006/JCAT.1997.1554