High Density of Free-Standing Holey Graphene/PPy Films for Superior Volumetric Capacitance of Supercapacitors.

作者: Zhimin Fan , Jianpeng Zhu , Xinghui Sun , Zhongjun Cheng , Yuyan Liu

DOI: 10.1021/ACSAMI.7B03477

关键词:

摘要: The volumetric performance is a vitally important metric for portable electronic and wearable devices with limited space. However, it contradictory the most supercapacitors in connection between gravimetric capacitances. Herein, we report simple strategy to prepare free-standing binder-free holey graphene/PPy film that possesses dense microstructure but still high own high-efficiency ion transport channels big ion-accessible surface area achieve high-powered supercapacitor electrodes, which have superior capacitance (416 F cm–3) (438 g–1) at 1.0 A g–1 6 M KOH electrolyte. Meanwhile, rate capability good cycling (82.4% retention even after 2000 cycles). Furthermore, energy density of assembled symmetric can show as 22.3 Wh L–1. Such densely packed free-s...

参考文章(57)
Xiaoliang Yu, Jiamin Lu, Changzhen Zhan, Ruitao Lv, Qinghua Liang, Zheng-Hong Huang, Wanci Shen, Feiyu Kang, Synthesis of activated carbon nanospheres with hierarchical porous structure for high volumetric performance supercapacitors Electrochimica Acta. ,vol. 182, pp. 908- 916 ,(2015) , 10.1016/J.ELECTACTA.2015.10.016
Yue Xu, Ying Tao, Xiaoyu Zheng, Hongyun Ma, Jiayan Luo, Feiyu Kang, Quan-Hong Yang, A Metal-Free Supercapacitor Electrode Material with a Record High Volumetric Capacitance over 800 F cm−3 Advanced Materials. ,vol. 27, pp. 8082- 8087 ,(2015) , 10.1002/ADMA.201504151
Naeyoung Jung, Soongeun Kwon, Dongwook Lee, Dong-Myung Yoon, Young Min Park, Anass Benayad, Jae-Young Choi, Jong Se Park, Synthesis of chemically bonded graphene/carbon nanotube composites and their application in large volumetric capacitance supercapacitors. Advanced Materials. ,vol. 25, pp. 6854- 6858 ,(2013) , 10.1002/ADMA.201302788
Ladislav Kavan, Jun-Ho Yum, Michael Grätzel, Graphene nanoplatelets outperforming platinum as the electrocatalyst in co-bipyridine-mediated dye-sensitized solar cells. Nano Letters. ,vol. 11, pp. 5501- 5506 ,(2011) , 10.1021/NL203329C
Jinhua Liu, Jing Yu, Jianrong Chen, Kaimin Shih, Noncovalent assembly of carbon nanoparticles and aptamer for sensitive detection of ATP RSC Advances. ,vol. 4, pp. 38199- 38205 ,(2014) , 10.1039/C4RA05631K
Michael Ghidiu, Maria R. Lukatskaya, Meng-Qiang Zhao, Yury Gogotsi, Michel W. Barsoum, Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance Nature. ,vol. 516, pp. 78- 81 ,(2014) , 10.1038/NATURE13970
Zhongqing Jiang, Zhong-jie Jiang, Xiaoning Tian, Weiheng Chen, Amine-functionalized holey graphene as a highly active metal-free catalyst for the oxygen reduction reaction Journal of Materials Chemistry. ,vol. 2, pp. 441- 450 ,(2014) , 10.1039/C3TA13832A
Yang Zhao, Jia Liu, Yue Hu, Huhu Cheng, Chuangang Hu, Changcheng Jiang, Lan Jiang, Anyuan Cao, Liangti Qu, Highly Compression‐Tolerant Supercapacitor Based on Polypyrrole‐mediated Graphene Foam Electrodes Advanced Materials. ,vol. 25, pp. 591- 595 ,(2013) , 10.1002/ADMA.201203578
Lijun Ren, Gaini Zhang, Jianfang Wang, Liping Kang, Zhibin Lei, Zhongwen Liu, Zhaotie Liu, Zhengping Hao, Zong–huai Liu, Adsorption–template preparation of polyanilines with different morphologies and their capacitance Electrochimica Acta. ,vol. 145, pp. 99- 108 ,(2014) , 10.1016/J.ELECTACTA.2014.08.088
Elçin Coşkun, Erasto A. Zaragoza-Contreras, Horacio J. Salavagione, Synthesis of sulfonated graphene/polyaniline composites with improved electroactivity Carbon. ,vol. 50, pp. 2235- 2243 ,(2012) , 10.1016/J.CARBON.2012.01.041