Inverted Polymer Solar Cells Integrated with a Low‐Temperature‐Annealed Sol‐Gel‐Derived ZnO Film as an Electron Transport Layer

作者: Yanming Sun , Jung Hwa Seo , Christopher J. Takacs , Jason Seifter , Alan J. Heeger

DOI: 10.1002/ADMA.201004301

关键词:

摘要: Highly efficient and air-stable inverted polymer solar cells are fabricated with a poly (2, 7-carbazole) derivative (PCDTBT): fullerene derivative (PC 70 BM) active layer. Low-temperature-annealed sol-gel-derived zinc oxide (ZnO) and molybdenum oxide films are selected as the electron and hole transporting layers, respectively. Power conversion efficiency (PCE) of 6.3% is demonstrated, which is the highest reported to date for inverted polymer solar cells.

参考文章(37)
Frederik C. Krebs, Torben D. Nielsen, Jan Fyenbo, Mads Wadstrøm, Marie S. Pedersen, Manufacture, integration and demonstration of polymer solar cells in a lamp for the “Lighting Africa” initiative Energy and Environmental Science. ,vol. 3, pp. 512- 525 ,(2010) , 10.1039/B918441D
G. Li, C.-W. Chu, V. Shrotriya, J. Huang, Y. Yang, Efficient inverted polymer solar cells Applied Physics Letters. ,vol. 88, pp. 253503- ,(2006) , 10.1063/1.2212270
Frederik C. Krebs, Suren A. Gevorgyan, Jan Alstrup, A roll-to-roll process to flexible polymer solar cells: model studies, manufacture and operational stability studies Journal of Materials Chemistry. ,vol. 19, pp. 5442- 5451 ,(2009) , 10.1039/B823001C
M. S. White, D. C. Olson, S. E. Shaheen, N. Kopidakis, D. S. Ginley, Inverted bulk-heterojunction organic photovoltaic device using a solution-derived ZnO underlayer Applied Physics Letters. ,vol. 89, pp. 143517- ,(2006) , 10.1063/1.2359579
Kion Norrman, Suren A. Gevorgyan, Frederik C. Krebs, Water-Induced Degradation of Polymer Solar Cells Studied by H218O Labeling ACS Applied Materials & Interfaces. ,vol. 1, pp. 102- 112 ,(2009) , 10.1021/AM800039W
Kenji Kawano, Roberto Pacios, Dmitry Poplavskyy, Jenny Nelson, Donal DC Bradley, James R Durrant, None, Degradation of organic solar cells due to air exposure Solar Energy Materials and Solar Cells. ,vol. 90, pp. 3520- 3530 ,(2006) , 10.1016/J.SOLMAT.2006.06.041
Chao-Hsiang Hsieh, Yen-Ju Cheng, Pei-Jung Li, Chiu-Hsiang Chen, Martin Dubosc, Ru-Meng Liang, Chain-Shu Hsu, Highly Efficient and Stable Inverted Polymer Solar Cells Integrated with a Cross-Linked Fullerene Material as an Interlayer Journal of the American Chemical Society. ,vol. 132, pp. 4887- 4893 ,(2010) , 10.1021/JA100236B
Shinuk Cho, Jung Hwa Seo, Sung Heum Park, Serge Beaupré, Mario Leclerc, Alan J. Heeger, A thermally stable semiconducting polymer. Advanced Materials. ,vol. 22, pp. 1253- 1257 ,(2010) , 10.1002/ADMA.200903420
Yongye Liang, Luping Yu, A New Class of Semiconducting Polymers for Bulk Heterojunction Solar Cells with Exceptionally High Performance Accounts of Chemical Research. ,vol. 43, pp. 1227- 1236 ,(2010) , 10.1021/AR1000296
W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology Advanced Functional Materials. ,vol. 15, pp. 1617- 1622 ,(2005) , 10.1002/ADFM.200500211