Partial oxidation of methane catalyzed by mo-incorporated SBA-1
作者： T. Tatsumi , N. Hamakawa , L.X. Dai
DOI: 10.1016/S0167-2991(00)80578-9
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摘要: The incorporation of Mo into the SBA-1 phase possessing a three-dimensional pore system has been studied under various acidic conditions using tetraethyl orthosilicate and hexadecyltriethylammonium cation. By adjusting pH, was effectively incorporated phase. Mo-SBA-1 active in partial oxidation methane to yield 5.2% formaldehyde with 61% selectivity.
sci-hub.se 参考文章(7)
C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, J. S. Beck, Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism Nature. ,vol. 359, pp. 710- 712 ,(1992) , 10.1038/359710A0
Qisheng Huo, David I. Margolese, Galen D. Stucky, Surfactant Control of Phases in the Synthesis of Mesoporous Silica-Based Materials Chemistry of Materials. ,vol. 8, pp. 1147- 1160 ,(1996) , 10.1021/CM960137H
Philip S. Casey, Trevor McAllister, Karl Foger, Selective Oxidation of Methane to Methanol at High Pressures Industrial & Engineering Chemistry Research. ,vol. 33, pp. 1120- 1125 ,(1994) , 10.1021/IE00029A008
Tsuneo Yanagisawa, Toshio Shimizu, Kazuyuki Kuroda, Chuzo Kato, The Preparation of Alkyltriinethylaininonium–Kaneinite Complexes and Their Conversion to Microporous Materials Bulletin of the Chemical Society of Japan. ,vol. 63, pp. 988- 992 ,(1990) , 10.1246/BCSJ.63.988
Wenzhong Zhang, Jialiang Wang, Peter T. Tanev, Thomas J. Pinnavaia, Catalytic hydroxylation of benzene over transition-metal substituted hexagonal mesoporous silicas Chemical Communications. pp. 979- 980 ,(1996) , 10.1039/CC9960000979
Keiko A. Koyano, Takashi Tatsumi, Synthesis of titanium-containing mesoporous molecular sieves with a cubic structure Chemical Communications. ,vol. 105, pp. 145- 146 ,(1996) , 10.1039/CC9960000145
M.S. Morey, A. Davidson, G.D. Stucky, Silica-Based, Cubic Mesostructures: Synthesis, Characterization and Relevance for Catalysis Journal of Porous Materials. ,vol. 5, pp. 195- 204 ,(1998) , 10.1023/A:1009626103498