Characterization of bionanocomposite films prepared with agar and paper-mulberry pulp nanocellulose

作者: Jeevan Prasad Reddy , Jong-Whan Rhim

DOI: 10.1016/J.CARBPOL.2014.04.056

关键词:

摘要: Crystallized nanocellulose (CNC) was separated from paper-mulberry (Broussonetia kazinoki Siebold) bast pulp by sulfuric acid hydrolysis method and they were blended with agar to prepare bionanocomposite films. The effect of CNC content (1, 3, 5 10 wt% based on agar) the mechanical, water vapor permeability (WVP), thermal properties nanocomposites studied. Changes cellulose fibers in structure, morphology, crystallinity, films evaluated using FT-IR, TEM, SEM, XRD, TGA analysis methods. composed fibrous spherical or elliptic granules nano-cellulose sizes 50-60 nm. Properties film such as mechanical barrier improved significantly (p<0.05) blending CNC. tensile modulus strength increased 40% 25%, respectively, composite CNC, WVP decreased 25% after formation nanocomposite 3 obtained can be used a reinforcing agent for preparation bio-nanocomposites, have high potential development completely biodegradable food packaging materials.

参考文章(46)
Tae-Ho Choi, Gang-Hyouk Lim, The Effects of the Cutting Length of Paper Mulberry Bast Fiber on Pulping and Hanji Properties(I) - White bast of Korea grown paper mulberry - Journal of Korea Technical Association of The Pulp and Paper Industry. ,vol. 40, pp. 57- 64 ,(2008)
Melissa B. Agustin, Bashir Ahmmad, Enna Richel P. De Leon, Jerico L. Buenaobra, Joel R. Salazar, Fumihiko Hirose, Starch-based biocomposite films reinforced with cellulose nanocrystals from garlic stalks Polymer Composites. ,vol. 34, pp. 1325- 1332 ,(2013) , 10.1002/PC.22546
Avik Khan, Ruhul A. Khan, Stephane Salmieri, Canh Le Tien, Bernard Riedl, Jean Bouchard, Gregory Chauve, Victor Tan, Musa R. Kamal, Monique Lacroix, Mechanical and barrier properties of nanocrystalline cellulose reinforced chitosan based nanocomposite films. Carbohydrate Polymers. ,vol. 90, pp. 1601- 1608 ,(2012) , 10.1016/J.CARBPOL.2012.07.037
X. Z. Tang, P. Kumar, S. Alavi, K. P. Sandeep, Recent Advances in Biopolymers and Biopolymer-Based Nanocomposites for Food Packaging Materials Critical Reviews in Food Science and Nutrition. ,vol. 52, pp. 426- 442 ,(2012) , 10.1080/10408398.2010.500508
Gilberto Siqueira, Julien Bras, Alain Dufresne, Cellulosic Bionanocomposites: A Review of Preparation, Properties and Applications Polymers. ,vol. 2, pp. 728- 765 ,(2010) , 10.3390/POLYM2040728
Kunal Das, Dipa Ray, NR Bandyopadhyay, Tony Ghosh, Amar K Mohanty, Manjusri Misra, None, A study of the mechanical, thermal and morphological properties of microcrystalline cellulose particles prepared from cotton slivers using different acid concentrations Cellulose. ,vol. 16, pp. 783- 793 ,(2009) , 10.1007/S10570-009-9280-6
Rongji Li, Jianming Fei, Yurong Cai, Yufeng Li, Jianqin Feng, Juming Yao, Cellulose whiskers extracted from mulberry: A novel biomass production Carbohydrate Polymers. ,vol. 76, pp. 94- 99 ,(2009) , 10.1016/J.CARBPOL.2008.09.034
Aristippos Gennadios, Curtis L. Weller, Charles H. Gooding, Measurement errors in water vapor permeability of highly permeable, hydrophilic edible films Journal of Food Engineering. ,vol. 21, pp. 395- 409 ,(1994) , 10.1016/0260-8774(94)90062-0
Andrea Sorrentino, Giuliana Gorrasi, Vittoria Vittoria, Potential perspectives of bio-nanocomposites for food packaging applications Trends in Food Science and Technology. ,vol. 18, pp. 84- 95 ,(2007) , 10.1016/J.TIFS.2006.09.004