Photochemistry of CS2/Cl complexes-combined pulse radiolysis-laser flash photolysis studies
作者： Takashi Sumiyoshi , Masayoshi Nakayama , Ryoko Fujiyoshi , Sadashi Sawamura
DOI: 10.1016/J.RADPHYSCHEM.2005.06.002
关键词:
摘要: Abstract Complexes of chlorine atoms and carbon disulfide (CS 2 ) were produced by pulse radiolysis CS in halocarbons photochemical reactions studied laser flash photolysis. Excitation /Cl complexes resulted rapid permanent photobleaching. The photobleaching is due to intermolecular atom abstraction CCl 4 with a quantum yield 0.04, while that ascribed hydrogen 1,2-dichloroethane has 0.21. effects additives are discussed based on the bond dissociation energy.
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