Synthesis of poly(n-butyl acrylate) containing multiblocks with a narrow molecular weight distribution using cyclic trithiocarbonates

作者: Ping Lei , Qi Wang , Jian Hong , Yixian Li

DOI: 10.1002/POLA.21721

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摘要: The polymerization of n-butyl acrylate in the presence two cyclic trithiocarbonates (CTTCs) and synthesis multiblock poly(n-butyl acrylate) have been investigated. CTTCs not only can be stepwise incorporated into polymer chain via reversible addition–fragmentation transfer (RAFT) but also polymerized polytrithiocarbonate, which functions as a macro-RAFT agent turn. Through kinds mechanisms, containing narrow-polydispersity blocks prepared. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Chem 44: 6600–6606,

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