In situ preparation of poly(ethylene terephthalate)-SiO2 nanocomposites

作者: Jiang-Ping He , Hua-Ming Li , Xia-Yu Wang , Yong Gao

DOI: 10.1016/J.EURPOLYMJ.2005.11.002

关键词:

摘要: Abstract Poly(ethylene terephthalate) (PET)/silica nanocomposites were synthesized by using the in situ polymerization approach. Sol–gel transformation based on hydrolysis and condensation of tetraethoxysilane (TEOS) is used to prepare inorganic phase, concurrent with terephthalic acid ethylene glycol produce PET matrix. Due simultaneous formation polymer matrix networks, a macrophase separation avoided, resulting materials have high degree homogeneity. The morphology crystallization behavior composites examined scanning electron microcopy (SEM) differential calorimetry (DSC), respectively.

参考文章(17)
Seok-Ho Hwang, Se-Woong Paeng, Jang-Yup Kim, Wansoo Huh, Sang-Won Lee, Synthesis of Allylester Resin Tethered to Layered Silicates by in-situ Polymerization and Its Nanocomposite Polymer Bulletin. ,vol. 49, pp. 329- 335 ,(2003) , 10.1007/S00289-002-0111-2
Guangming Chen, Zongneng Qi, Deyan Shen, Shear-induced ordered structure in polystyrene/clay nanocomposite Journal of Materials Research. ,vol. 15, pp. 351- 356 ,(2000) , 10.1557/JMR.2000.0055
J. Mrowiec-Białoń, A.I. Lachowski, A.B. Jarzȩbski, L.G. Gordeeva, Y.I. Aristov, SiO2–LiBr Nanocomposite Sol–Gel Adsorbents of Water Vapor: Preparation and Properties joint international conference on information sciences. ,vol. 218, pp. 500- 503 ,(1999) , 10.1006/JCIS.1999.6406
Hatsuo Ishida, Sandi Campbell, John Blackwell, General approach to nanocomposite preparation Chemistry of Materials. ,vol. 12, pp. 1260- 1267 ,(1999) , 10.1021/CM990479Y
LS Sales, PA Robles-Dutenhefner, DL Nunes, NDS Mohallem, EV Gusevskaya, EMB Sousa, None, Characterization and catalytic activity studies of sol-gel Co-SiO2 nanocomposites Materials Characterization. ,vol. 50, pp. 95- 99 ,(2003) , 10.1016/S1044-5803(03)00073-1
Jeffrey W. Gilman, Catheryn L. Jackson, Alexander B. Morgan, Richard Harris, Evangelos Manias, Emmanuel P. Giannelis, Melanie Wuthenow, Dawn Hilton, Shawn H. Phillips, Flammability Properties of Polymer - Layered-Silicate Nanocomposites. Polypropylene and Polystyrene Nanocomposites Chemistry of Materials. ,vol. 12, pp. 1866- 1873 ,(2000) , 10.1021/CM0001760
Y. Liu, J.Y. Lee, L. Hong, In situ preparation of poly(ethylene oxide)–SiO2 composite polymer electrolytes Journal of Power Sources. ,vol. 129, pp. 303- 311 ,(2004) , 10.1016/J.JPOWSOUR.2003.11.026
Tong Wan, Ling Chen, Yang Choo Chua, Xuehong Lu, Crystalline morphology and isothermal crystallization kinetics of poly(ethylene terephthalate)/clay nanocomposites Journal of Applied Polymer Science. ,vol. 94, pp. 1381- 1388 ,(2004) , 10.1002/APP.20975
Emmanuel P. Giannelis, Polymer Layered Silicate Nanocomposites Advanced Materials. ,vol. 8, pp. 29- 35 ,(1996) , 10.1002/ADMA.19960080104
E. R. Leite, N. L. V. Carreño, E. Longo, F. M. Pontes, A. Barison, A. G. Ferreira, Y. Maniette, J. A. Varela, Development of metal - SiO2 nanocomposites in a single-step process by the polymerizable complex method Chemistry of Materials. ,vol. 14, pp. 3722- 3729 ,(2002) , 10.1021/CM0203767