Large magnetoelectric effects mediated by electric-field-driven nanoscale phase transformations in sputtered (nanoparticulate) and electrochemically dealloyed (nanoporous) Fe–Cu films

作者: Shauna Robbennolt , Alberto Quintana , Eva Pellicer , Jordi Sort

DOI: 10.1039/C8NR03924K

关键词:

摘要: Large magnetoelectric effects are observed in as-sputtered (nanoparticulate-like) and electrochemically dealloyed (nanoporous) 200 nm thick Fe–Cu films. Application of positive voltages decreases both the saturation magnetization (MS) coercivity (HC) films, while negative cause reverse effect (increase MS HC). The relative variations as high 20% for beyond 100% HC, states. These changes magnetic properties caused by controlled reversible electric-field-driven nanoscale phase transformations between face-centered cubic (fcc) body-centered (bcc) structures. transitions turn due to selective redox reactions induced applied voltage, which can be regarded a “magnetoionic effect.” tuning HC with moderate values together sustainable composition investigated alloys (not containing noble metals, opposed many previous works on thin films), pave way towards implementation spintronic devices enhanced energy efficiency functionalities.

参考文章(47)
Alain Karma, Nikolay Dimitrov, Karl Sieradzki, Jonah Erlebacher, Michael J. Aziz, Evolution of nanoporosity in dealloying Nature. ,vol. 410, pp. 450- 453 ,(2001) , 10.1038/35068529
J. Y. Huang, J. Z. Jiang, H. Yasuda, H. Mori, Kinetic process of mechanical alloying in Fe 50 Cu 50 Physical Review B. ,vol. 58, pp. 11817- 11820 ,(1998) , 10.1103/PHYSREVB.58.R11817
Oya Okman, Dongyun Lee, Jeffrey W. Kysar, Fabrication of crack-free nanoporous gold blanket thin films by potentiostatic dealloying Scripta Materialia. ,vol. 63, pp. 1005- 1008 ,(2010) , 10.1016/J.SCRIPTAMAT.2010.07.025
H. Rösner, S. Parida, D. Kramer, C. A. Volkert, J. Weissmüller, Reconstructing a Nanoporous Metal in Three Dimensions: An Electron Tomography Study of Dealloyed Gold Leaf Advanced Engineering Materials. ,vol. 9, pp. 535- 541 ,(2007) , 10.1002/ADEM.200700063
Li Sun, Chia-Ling Chien, Peter C. Searson, Fabrication of Nanoporous Nickel by Electrochemical Dealloying Chemistry of Materials. ,vol. 16, pp. 3125- 3129 ,(2004) , 10.1021/CM0497881
Iris E. Rauda, Raffaella Buonsanti, Laura C. Saldarriaga-Lopez, Kanokraj Benjauthrit, Laura T. Schelhas, Morgan Stefik, Veronica Augustyn, Jesse Ko, Bruce Dunn, Ulrich Wiesner, Delia J. Milliron, Sarah H. Tolbert, General Method for the Synthesis of Hierarchical Nanocrystal-Based Mesoporous Materials ACS Nano. ,vol. 6, pp. 6386- 6399 ,(2012) , 10.1021/NN302789R
F. Bonell, S. Murakami, Y. Shiota, T. Nozaki, T. Shinjo, Y. Suzuki, Large change in perpendicular magnetic anisotropy induced by an electric field in FePd ultrathin films Applied Physics Letters. ,vol. 98, pp. 232510- ,(2011) , 10.1063/1.3599492
Doretta Capsoni, Marcella Bini, Stefania Ferrari, Eliana Quartarone, Piercarlo Mustarelli, Recent advances in the development of Li–air batteries Journal of Power Sources. ,vol. 220, pp. 253- 263 ,(2012) , 10.1016/J.JPOWSOUR.2012.07.123
Plinio Innocenzi, Luca Malfatti, None, Mesoporous thin films: properties and applications Chemical Society Reviews. ,vol. 42, pp. 4198- 4216 ,(2013) , 10.1039/C3CS35377J