Makrobicyclische Endorezeptoren: Synthese, Kristallstruktur und Einschluß organischer Gastmoleküle

作者: Ingo Lüer , Kari Rissanen , Fritz Vögtle

DOI: 10.1002/CBER.19921250814

关键词:

摘要: Macrobicyclic Endoreceptors: Synthesis, Crystal Structure, and Inclusion of Organic Guests The macrobicyclic ligand 2 is synthesized in a one-step cyclization procedure. According to an X-ray structure analysis three dichloromethane guest molecules are included inside the cavity, whereas water methanol found outside cavity. The rigid endo preorganization nitrogen donors allows complexation 2,9-disubstituted 1,10-phenanthrolines

参考文章(28)
Frank Ebmeyer, Fritz Vögtle, On the Way from Small to Very Large Molecular Cavities Bioorganic Chemistry Frontiers. pp. 143- 159 ,(1990) , 10.1007/978-3-642-75256-8_4
Steven J. Keipert, Carolyn B. Knobler, Donald J. Cram, Host-guest complexation Tetrahedron. ,vol. 43, pp. 4861- 4874 ,(1987) , 10.1016/S0040-4020(01)87669-9
C.O Dietrich-Buchecker, J.P Sauvage, Synthese de composes polyethers macrocycliques derives de la phenanthroline-1,10 diphenyl-2,9. Tetrahedron Letters. ,vol. 24, pp. 5091- 5094 ,(1983) , 10.1016/S0040-4039(00)94049-8
Francis Bitsch, Christiane O. Dietrich-Buchecker, Abdel Kader Khemiss, Jean Pierre Sauvage, Alain Van Dorsselaer, Multiring interlocked systems: structure elucidation by electrospray mass spectrometry Journal of the American Chemical Society. ,vol. 113, pp. 4023- 4025 ,(1991) , 10.1021/JA00010A072
Norbert Sendhoff, Wolfram Kißener, Fritz Vögtle, Sybille Franken, Heinrich Puff, Drei- und sechsfach verbrückte phenyloge Cyclophane Chemische Berichte. ,vol. 121, pp. 2179- 2185 ,(1988) , 10.1002/CBER.19881211217
Marye Anne Fox, PHOTOINDUCED ELECTRON TRANSFER Photochemistry and Photobiology. ,vol. 52, pp. 617- 627 ,(1990) , 10.1111/J.1751-1097.1990.TB01808.X
Christopher J. Chandler, Leslie W. Deady, James A. Reiss, Macrocyclic polyether- and polythioether-diesters and dithioesters from 1,10-phenanthroline-2,9-dicarboxylic acid Journal of Heterocyclic Chemistry. ,vol. 23, pp. 1327- 1330 ,(1986) , 10.1002/JHET.5570230511
Fritz Vögtle, Michael Zuber, Rainer G. Lichtenthaler, Notiz über ein vereinfachtes Verfahren zur Darstellung von 1,3,5-Tris(brommethyl)benzol Chemische Berichte. ,vol. 106, pp. 717- 718 ,(1973) , 10.1002/CBER.19731060238
G. R. Newkome, W. E. Puckett, T. Vreeland, G. E. Kiefer, α-Methyl functionalization of electron-poor heterocycles: 2,9-bis(chloromethyl)-1,10-phenanthroline. Synthesis of a [3.3]cyclophane containing the 1,10-phenanthrolino moiety Journal of Organic Chemistry. ,vol. 48, pp. 5112- 5114 ,(1983)
Smaragda Grammenudi, Fritz Vögtle, Große Molekülhohlräume für kleine Ionen – doppelte Verbrückung dreier Bipyridin‐Einheiten Angewandte Chemie. ,vol. 98, pp. 1119- 1121 ,(1986) , 10.1002/ANGE.19860981224