The Catalyst Precursor, Catalyst, and Intermediate in the RuII-Promoted Asymmetric Hydrogen Transfer between Alcohols and Ketones

作者: Karl-Josef Haack , Shohei Hashiguchi , Akio Fujii , Takao Ikariya , Ryoji Noyori

DOI: 10.1002/ANIE.199702851

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摘要: … a very rare catalytic system in asymmetric transformations for which both the true catalyst and … First, the catalyst precursor 1 was prepared as orange crystals in > 90 % yield by reacting [(…

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