Characterization of the adsorbed layer of a mixture of nonionic and cationic hydrocarbon surfactants on silica

作者: K. Esumi , T. Nagahama , K. Meguro

DOI: 10.1007/BF00652536

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摘要: The adsorption of hexadecyl trimethylammonium bromide (HDTAB) and nonylphenyl polyglycol ether (NP20) from mixed aqueous solutions on silica has been investigated. is enhanced at low concentration, but decreased high concentration compared with those the single surfactants. Further, measurements fluorescence spectra pyrene-3-carboxaldehyde ESR 2,2,6,6-tetramethylpiperidinyl-1-oxy in surfactant adsorbed layer indicate that micropolarity affected by feed mole fraction HDTAB, particular over range 0.3–0.7, while microviscosity almost constant same a concentration. This suggests range, ratio HDTAB/NP20 second same.

参考文章(16)
A. R. Rennie, E. M. Lee, E. A. Simister, R. K. Thomas, Structure of a cationic surfactant layer at the silica-water interface Langmuir. ,vol. 6, pp. 1031- 1034 ,(1990) , 10.1021/LA00095A025
J.F Scamehorn, R.S Schechter, W.H Wade, Adsorption of surfactants on mineral oxide surfaces from aqueous solutions: III. Binary mixtures of anionic and nonionic surfactants Journal of Colloid and Interface Science. ,vol. 85, pp. 494- 501 ,(1982) , 10.1016/0021-9797(82)90015-7
K. Kalyanasundaram, J. K. Thomas, Solvent-dependent fluorescence of pyrene-3-carboxaldehyde and its applications in the estimation of polarity at micelle-water interfaces The Journal of Physical Chemistry. ,vol. 81, pp. 2176- 2180 ,(1977) , 10.1021/J100538A008
M. J. Schwuger, H. G. Smolka, Mixed adsorption of ionic and nonionic surfactants on active carbon Colloid and Polymer Science. ,vol. 255, pp. 589- 594 ,(1977) , 10.1007/BF01549746
Cuong M Nguyen, James F Rathman, John F Scamehorn, Thermodynamics of mixed micelle formation Journal of Colloid and Interface Science. ,vol. 112, pp. 438- 446 ,(1986) , 10.1016/0021-9797(86)90112-8
K. Kalyanasundaram, J. K. Thomas, Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems Journal of the American Chemical Society. ,vol. 99, pp. 2039- 2044 ,(1977) , 10.1021/JA00449A004
Michael J. Hey, John W. Mactaggart, Colin H. Rochester, Mixed adsorption of a non-ionic and an anionic surfactant at the carbon–aqueous solution interface Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 82, pp. 1805- 1811 ,(1986) , 10.1039/F19868201805
J. Martinie, J. Michon, A. Rassat, Nitroxides. LXX. Electron spin resonance study of cyclodextrin inclusion compounds Journal of the American Chemical Society. ,vol. 97, pp. 1818- 1823 ,(1975) , 10.1021/JA00840A037