Potentiostatic and potentiodynamic studies on the Kolbe electro-synthesis
作者： A. K. Vijh , B. E. Conway
DOI: 10.1007/BF00510141
关键词:
摘要: Electrode kinetic approaches have been applied to the investigation of Kolbe reaction on gold in “non-aqueous” (glacial acetic acid) solutions and anodic reactions which proceed aqueous (acidic) potassium acetate (1 M) solutions. Characterisation products under potentiostatic conditions confirms that does not with any detectable efficiency solutions; oxygen evolution is major process. Mechanisms are discussed terms analysis steady-state kinetics conditions. Conclusions regarding identity adsorbed intermediates, thence mechanisms based cathodic transients.
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