Synthesis and study of ammonium hexamolybdooxalatovanadate

作者: A. V. Oreshkina , G. Z. Kaziev

DOI: 10.1134/S0036023610010067

关键词:

摘要: Ammonium hexamolybdooxalatovanadate of the composition (NH4)3[V(C2O4)Mo6O18(OH)6] · 3H2O (I) has been synthesized and studied by mass spectroscopy, IR thermogravimetry, X_ray powder diffraction. Crystals I are monoclinic with unit cell parameters a = 11.9737 A, b 18.6533 c 11.2178 β 121.021°, V 3162. 95 A3, M 1214.01 g/mol, ρcalcd 1.91 g/cm3, Z 3.

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