Photochemical Reactions of Surfactant Molecules in Condensed Monolayer Assemblies—Environmental Control and Modification of Reactivity†
作者： David G. Whitten
关键词:
摘要: An investigation of the effects a controlled microenvironment on reactivity has been carried out by synthesis and study in organized monolayers surfactant molecules containing photochemically reactive chromophores. Reactions where substantial environmental have observed include cis-trans isomerization olefins, ketone photoeliminations, ligand substitution processes, excimer photodimer formation, photoredox reactions. Both reactions occurring within assemblies as well interfacial phenomena investigated. Results obtained these studies suggest possible extensions applications for development new catalyst systems, biological models syntheses.
sci-hub.se 参考文章(69)
Gerhard Sprintschnik, Hertha W. Sprintschnik, Pierre P. Kirsch, David G. Whitten, Photochemical reactions in organized monolayer assemblies. III. Photochemical cleavage of water: a system for solar energy conversion using monolayer-bound transition metal complexes Journal of the American Chemical Society. ,vol. 98, pp. 2337- 2338 ,(1976) , 10.1021/JA00424A057
Irwin A. Cohen, Dimeric nature of hemin hydroxides Journal of the American Chemical Society. ,vol. 91, pp. 1980- 1983 ,(1969) , 10.1021/JA01036A020
F. R. Hopf, D. Moebius, D. G. Whitten, Environmental control of reactions: enhancement of .mu.-oxo dimer formation from iron(III) porphyrins in organized monolayer assemblies as a model for membrane catalysis Journal of the American Chemical Society. ,vol. 98, pp. 1585- ,(1976) , 10.1021/JA00422A054
David G. Whitten, Joseph C. N. Yau, F. A. Carroll, Photochemistry and oxidation-reduction reactions of tin porphyrins Journal of the American Chemical Society. ,vol. 93, pp. 2291- 2296 ,(1971) , 10.1021/JA00738A031
Chin-Tung Lin, Norman Sutin, Quenching of the luminescence of the tris(2,2'-bipyridine) complexes of ruthenium(II) and osmium(II). Kinetic considerations and photogalvanic effects The Journal of Physical Chemistry. ,vol. 80, pp. 97- 105 ,(1976) , 10.1021/J100543A002
Patricia J. DeLaive, J. T. Lee, Hertha W. Sprintschnik, H. Abruna, T. J. Meyer, David G. Whitten, Photoinduced redox reactions of hydrophobic ruthenium(II) complexes Journal of the American Chemical Society. ,vol. 99, pp. 7094- 7097 ,(1977) , 10.1021/JA00463A070
Dina. Gegiou, K. A. Muszkat, Ernst. Fischer, Temperature dependence of photoisomerization. VI. Viscosity effect Journal of the American Chemical Society. ,vol. 90, pp. 12- 18 ,(1968) , 10.1021/JA01003A003
Nicholas J. Turro, Kou-Chang Liu, Ming-Fea Chow, SOLVENT SENSITIVITY OF TYPE II PHOTOREACTIONS OF KETONES AS A DEVICE TO PROBE SOLUTE LOCATION IN MICELLES Photochemistry and Photobiology. ,vol. 26, pp. 413- 415 ,(1977) , 10.1111/J.1751-1097.1977.TB07507.X
B. M. Hoffman, Q. H. Gibson, On the photosensitivity of liganded hemoproteins and their metal-substituted analogues. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 75, pp. 21- 25 ,(1978) , 10.1073/PNAS.75.1.21
Asher. Elgavi, Bernard S. Green, G. M. J. Schmidt, Reactions in chiral crystals. Optically active heterophotodimer formation from chiral single crystals Journal of the American Chemical Society. ,vol. 95, pp. 2058- 2059 ,(1973) , 10.1021/JA00787A081