A model for the CO-inhibited form of [NiFe] hydrogenase: synthesis of (CO)3Fe(μ-StBu)3Ni{SC6H3-2,6-(mesityl)2} and reversible CO addition at the Ni site
作者： Y. Ohki , K. Yasumura , M. Ando , S. Shimokata , K. Tatsumi
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摘要: A [NiFe] hydrogenase model compound having a distorted trigonal-pyramidal nickel center, (CO) 3 Fe(μ-S t Bu) 3 Ni(SDmp), 1 (Dmp = C 6 H 3 -2,6-(mesityl) 2 ), was synthesized from …
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