Iridium-catalyzed asymmetric ring-opening reactions of azabenzonorbornadiene with carboxylic acid nucleophiles
作者： Yuhua Long , Wenling Wang , Dingqiao Yang , Han Jiang , Kaixuan Chen
DOI: 10.1007/S11030-013-9491-5
关键词:
摘要: Iridium-catalyzed asymmetric ring-opening reaction of $$N$$ -substituted azabenzonorbornadienes with various carboxylic acids has been developed. The offered trans-1,2-dihydronaphthalene products containing an allylic carboxylate moiety in moderate yields (up to 89 %) high enantioselectivities 96 %). trans-configuration the was confirmed by X-ray crystallography.
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