Complexes of organothallium(III) with Cis-1,2-dicyanoethylenedithiolate ion and a ‘tripod’ ligand. Synthesis, infrared and proton magnetic resonance spectra and reactivity
作者： Gian Carlo Stocco , Annamaria Venezia
DOI: 10.1016/S0020-1693(00)84160-2
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摘要: Abstract The reaction of cis-1,2-dicyanoethylenedithiolate ion (mnt2− with organothallium(III) derivatives has been examined. complexes [(CH3)2Tl]2mnt and [(C4H9)4N] [(C6H5)2Tl mnt] have synthesized. results seem to indicate a trend in reactivity similar that arylmercury(II) towards chelating agents nucleophilic character. In addition, the complex [(CH3)2Tl(tren)] [BPh4] obtained as test complexing ability 2,2′, 2″-triaminotriethylamine(tren) organometallic moieties. I.r. 1H n.m.r. are presented discussed.
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