Preparation and characterization of transparent polyarylethers-silica hybrid membranes with covalently connected phases
作者： Wei Wei , Haibo Zhang , Shaowei Guan , Zhenhua Jiang , Xigui Yue
DOI: 10.1016/J.POLYMER.2012.08.059
关键词:
摘要: Abstract From the molecular designing point of view, (p-amino)phenylhydroquinone (APH) and (3, 5-dimethoxy)phenylhydroquinone (DMPH) were prepared in a two-step synthesis. Polyetheretherketone with large number amino groups (APEEK) polyethersulfone quantities hydroxyl side (HPES) successfully synthesized from these bisphenol monomers. The functionalized polyarylethers then grafted by isocyanatopropyltriethoxysilane (IPTS) through in-situ O -acylation reaction to obtained triethoxysilyl groups. Subsequently, hydrolyzed formed network produced covalent bonds between organic inorganic phases via sol–gel process under acid condition. Transparent polyarylether-silica (PAE-silica) hybrid films fabricated this process. Furthermore, tetraethylorthosilicate (TEOS) SiO 2 nanoparticles introduced as silica sources improve content silica. generated hydrolysis on IPTS modified was covalently connected substrates. present method achieved transparent at high 40 wt%, which resulted closely combination homogenous distribution particles polymer matrix.
sci-hub.se 参考文章(48)
Pellegrino Musto, Giuseppe Ragosta, Gennaro Scarinzi, Leno Mascia, Polyimide-silica nanocomposites: spectroscopic, morphological and mechanical investigations Polymer. ,vol. 45, pp. 1697- 1706 ,(2004) , 10.1016/J.POLYMER.2003.12.044
Wei-Lun Chang, Hung-Wei Su, Wen-Chang Chen, Synthesis and properties of photosensitive polyimide–nanocrystalline titania optical thin films European Polymer Journal. ,vol. 45, pp. 2749- 2759 ,(2009) , 10.1016/J.EURPOLYMJ.2009.06.016
Chris J Cornelius, Eva Marand, Hybrid inorganic-organic materials based on a 6FDA-6FpDA-DABA polyimide and silica: Physical characterization studies Polymer. ,vol. 43, pp. 2385- 2400 ,(2002) , 10.1016/S0032-3861(01)00803-5
Yinghua Qi, Jianfu Ding, Michael Day, Jia Jiang, Claire L. Callender, Cross-linkable highly fluorinated poly(arylene ether ketones/sulfones) for optical waveguiding applications Chemistry of Materials. ,vol. 17, pp. 676- 682 ,(2005) , 10.1021/CM048587U
Jorphin Joseph, Chi-Yung Tseng, Chun-Jern Pan, Hung-Ming Chen, Chi-Wen Lin, K. Chandrasekara Pillai, Bing-Joe Hwang, Growing well-defined monodispersed silica in polyimide host membranes using a surfactant assisted sol-gel process Polymer. ,vol. 51, pp. 5663- 5668 ,(2010) , 10.1016/J.POLYMER.2010.09.064
Tanzeela Nazir, Adeel Afzal, Humaira M Siddiqi, Zahoor Ahmad, Michel Dumon, None, Thermally and mechanically superior hybrid epoxy-silica polymer films via sol-gel method Progress in Organic Coatings. ,vol. 69, pp. 100- 106 ,(2010) , 10.1016/J.PORGCOAT.2010.05.012
Jae Hoon Kim, Young Moo Lee, Gas permeation properties of poly(amide-6-b-ethylene oxide)–silica hybrid membranes Journal of Membrane Science. ,vol. 193, pp. 209- 225 ,(2001) , 10.1016/S0376-7388(01)00514-2
Sung Hyun Kim, Ki Bong Lee, Ki Tae Park, Sang Gon Kim, Jeong Hwan Chun, Dong Hyun Jo, Byung-Hee Chun, Woo In Jang, Gyung Bo Kang, Composite membranes based on a sulfonated poly(arylene ether sulfone) and proton-conducting hybrid silica particles for high temperature PEMFCs International Journal of Hydrogen Energy. ,vol. 36, pp. 10891- 10900 ,(2011) , 10.1016/J.IJHYDENE.2011.05.151
Yan Gao, Gilles P. Robertson, Michael D. Guiver, Serguei D. Mikhailenko, Xiang Li, Serge Kaliaguine, Synthesis of Poly(arylene ether ether ketone ketone) Copolymers Containing Pendant Sulfonic Acid Groups Bonded to Naphthalene as Proton Exchange Membrane Materials Macromolecules. ,vol. 37, pp. 6748- 6754 ,(2004) , 10.1021/MA049971F
Holger Petersen, Petra M. Fechner, Dagmar Fischer, Thomas Kissel, Synthesis, Characterization, and Biocompatibility of Polyethylenimine-graft-poly(ethylene glycol) Block Copolymers Macromolecules. ,vol. 35, pp. 6867- 6874 ,(2002) , 10.1021/MA012060A