Energetics of the loss of H2 from [C3H7]+
作者： Phillip T. Mead , John C. Traeger , John R. Christie , Peter. J. Derrick
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摘要: The internal energies of [C3H7]+ ions contributing to the metastable peak [C3H5]+ + H2 are higher (by perhaps > 100 kJ mol−1) than those ion threshold current in appearance energy measurements on [C3H5]+. measured may lead an underestimation activation energy, i.e. negative ‘kinetic shift’, due quantum, mechanical tunnelling. distribution released decomposition can be explained basis that much reverse and a statistical proportion excess is as translation.
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