Effects of air oxidation on the evolution of surface area within nuclear graphite and the contribution of macropores

作者: Joshua J. Kane , Austin C. Matthews , W. David Swank , William E. Windes

DOI: 10.1016/J.CARBON.2020.05.018

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摘要: Abstract Reactive surface area and its evolution play an important role in the oxidation behavior of porous carbon materials. Here, reactive within nuclear graphite grades NBG-18, IG-110, PCEA were examined using chronic experiments interrupted with short thermal gravimetric analyses. To help interpret observed changes area, contribution macropore total was estimated X-ray computed tomography repeated morphological dilations digitally isolated pore structure. For these graphites, by more than order magnitude between 0 70% conversion. Surface roughening, opening evolution, as well late exposure filler material likely contribute to graphites.

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