Infrared spectroscopy of goethite dehydroxylation. II. Effect of aluminium substitution on the behaviour of hydroxyl units

作者: H.D Ruan , R.L Frost , J.T Kloprogge , L Duong

DOI: 10.1016/S1386-1425(01)00556-X

关键词:

摘要: Dehydroxylation of goethite as affected by aluminium substitution was investigated using Fourier transform infrared spectroscopy (FT–IR) in conjunction with X-ray diffraction (XRD), thermogravimetric analysis (TGA) and differential thermogravimetric analysis (DTGA). The band intensities of hydroxyl vibrations were indicative of the degree of dehydroxylation and the changes in band parameters due to aluminium substitution were observed. The effect of aluminium substitution on band parameters of FT–IR spectra of goethite and its partially and …

参考文章(27)
T. Grygar, I. H. D. Ruan, R. J. Gilkes, Re-examination of the kinetics of the thermal dehydroxylation of goethite Journal of Thermal Analysis and Calorimetry. ,vol. 55, pp. 301- 309 ,(1999) , 10.1023/A:1010181416785
Özden Özdemir, David J. Dunlop, Intermediate magnetite formation during dehydration of goethite Earth and Planetary Science Letters. ,vol. 177, pp. 59- 67 ,(2000) , 10.1016/S0012-821X(00)00032-7
D.G. Lewis, U. Schwertmann, The effect of [OH] on the goethite produced from ferrihydrite under alkaline conditions joint international conference on information sciences. ,vol. 78, pp. 543- 553 ,(1980) , 10.1016/0021-9797(80)90591-3
Udo Schwertmann, Josef Friedl, Helge Stanjek, Darrell G Schulze, The Effect of Al on Fe Oxides. XIX. Formation of Al-Substituted Hematite from Ferrihydrite at 25°C and pH 4 To 7 Clays and Clay Minerals. ,vol. 48, pp. 159- 172 ,(2000) , 10.1346/CCMN.2000.0480202
W. R. Fischer, The Formation of Hematite from Amorphous Iron(III)Hydroxide Clays and Clay Minerals. ,vol. 23, pp. 33- 37 ,(1975) , 10.1346/CCMN.1975.0230105
Emilia Wolska, Wojciech Szajda, Structural and spectroscopic characteristics of synthetic hydrohaematite Journal of Materials Science. ,vol. 20, pp. 4407- 4412 ,(1985) , 10.1007/BF00559329
H. D. Ruan, R. J. Gilkes, Kinetics of thermal dehydroxylation of aluminous goethite Journal of Thermal Analysis and Calorimetry. ,vol. 46, pp. 1223- 1238 ,(1996) , 10.1007/BF01979237