A mechanistic study of nitrous oxide adsorption and decomposition on zirconia
作者： T.M. Miller , V.H. Grassian
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摘要: FT-IR spectroscopy and mass spectrometry have been used to study the adsorption decomposition of nitrous oxide on zirconia. It was determined that zirconia cations in 4+ oxidation state are site for molecular N2O, whereas Zr3+ sites active toward dissociative N2O at temperatures as low 25°C. Catalytic ZrO2 occurs above 350°C follows first-order reaction kinetics. Experiments utilizing isotopic labeling conjunction with were done elucidate details mechanism. Based results presented here, a mechanism is proposed.
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