Process dependent graphene/MnO2 composites for supercapacitors

作者: Myeongjin Kim , Yongseon Hwang , Jooheon Kim

DOI: 10.1016/J.CEJ.2013.06.095

关键词:

摘要: Abstract Two types of graphene/MnO 2 composites were synthesized by different reaction procedures. S1 was as follows: first, nanoneedle MnO formed on the GO sheets using various functional groups (GO/MnO ). In second stage, GO/MnO reduced to (S1) via dipping method. S2 a order: graphene oxide and sheets. The morphology microstructure as-prepared characterized X-ray diffractometery, field-emission scanning electron microscopy, photoelectron spectroscopy, thermogravimetric analysis. Characterization indicated that structures in composite homogeneously dispersed sheets, whereas aggregates due absence groups. capacitive properties electrodes measured cyclic voltammetry, galvanostatic charge/discharge tests, electrochemical impedance spectroscopy three-electrode experimental setup with an aqueous solution 1 M Na SO 4 electrolyte. electrode exhibited specific capacitance high 327.5 F g −1 at 10 mV s , which higher than (229.9 F g It is anticipated formation surface following reduction procedure could be promising fabrication method for supercapacitor electrodes.

参考文章(32)
Mehul N. Patel, Xiqing Wang, Brian Wilson, Domingo A. Ferrer, Sheng Dai, Keith J. Stevenson, Keith P. Johnston, Hybrid MnO2–disordered mesoporous carbon nanocomposites: synthesis and characterization as electrochemical pseudocapacitor electrodes Journal of Materials Chemistry. ,vol. 20, pp. 390- 398 ,(2010) , 10.1039/B915370E
Sheng Chen, Junwu Zhu, Qiaofeng Han, Zhijun Zheng, Yong Yang, Xin Wang, Shape-Controlled Synthesis of One-Dimensional MnO2 via a Facile Quick-Precipitation Procedure and its Electrochemical Properties Crystal Growth & Design. ,vol. 9, pp. 4356- 4361 ,(2009) , 10.1021/CG900223F
Sang-Bok Ma, Kyung-Wan Nam, Won-Sub Yoon, Xiao-Qing Yang, Kyun-Young Ahn, Ki-Hwan Oh, Kwang-Bum Kim, Electrochemical properties of manganese oxide coated onto carbon nanotubes for energy-storage applications Journal of Power Sources. ,vol. 178, pp. 483- 489 ,(2008) , 10.1016/J.JPOWSOUR.2007.12.027
Zhangpeng Li, Yongjuan Mi, Xiaohong Liu, Sheng Liu, Shengrong Yang, Jinqing Wang, Flexible graphene/MnO2 composite papers for supercapacitor electrodes Journal of Materials Chemistry. ,vol. 21, pp. 14706- 14711 ,(2011) , 10.1039/C1JM11941A
Jun Yan, Zhuangjun Fan, Tong Wei, Weizhong Qian, Milin Zhang, Fei Wei, Fast and reversible surface redox reaction of graphene–MnO2 composites as supercapacitor electrodes Carbon. ,vol. 48, pp. 3825- 3833 ,(2010) , 10.1016/J.CARBON.2010.06.047
Ling Qiu, Xiaowei Yang, Xinglong Gou, Wenrong Yang, Zi-Feng Ma, Gordon G. Wallace, Dan Li, Dispersing Carbon Nanotubes with Graphene Oxide in Water and Synergistic Effects between Graphene Derivatives Chemistry: A European Journal. ,vol. 16, pp. 10653- 10658 ,(2010) , 10.1002/CHEM.201001771
Chao Xu, Xin Wang, Junwu Zhu, Graphene−Metal Particle Nanocomposites Journal of Physical Chemistry C. ,vol. 112, pp. 19841- 19845 ,(2008) , 10.1021/JP807989B
Hernan Sanchez Casalongue, Hongjie Dai, Hailiang Wang, Yongye Liang, Ni(OH)2 Nanoplates Grown on Graphene as Advanced Electrochemical Pseudocapacitor Materials Journal of the American Chemical Society. ,vol. 132, pp. 7472- 7477 ,(2010) , 10.1021/JA102267J
Shinichi Komaba, Atsushi Ogata, Tomoya Tsuchikawa, Enhanced supercapacitive behaviors of birnessite Electrochemistry Communications. ,vol. 10, pp. 1435- 1437 ,(2008) , 10.1016/J.ELECOM.2008.07.025
Sheng Chen, Junwu Zhu, Xiaodong Wu, Qiaofeng Han, Xin Wang, Graphene Oxide−MnO2 Nanocomposites for Supercapacitors ACS Nano. ,vol. 4, pp. 2822- 2830 ,(2010) , 10.1021/NN901311T