A new method for reactivating the supported deep hydrotreatment CoMo/Al2O3 and NiMo/Al2O3 catalysts after oxidative regeneration
作者： S. V. Budukva , O. V. Klimov , A. S. Noskov
DOI: 10.1134/S2070050415030034
关键词:
摘要: A new method for the reactivation of CoMo/Al2O3 and NiMo/Al2O3 catalysts deep hydrotreatment diesel fuel after oxidative regeneration stage involves impregnating regenerated with aqueous solutions such chelating compounds as citric oxalic acids, ethyleneglycol, diethyleneglycol subsequent drying. The activity reactivated subjected to treatment can be higher than fresh samples. effect nature amount introduced chelates on IK-GO-1 catalyst in straight-run is studied. Treating an oxidized sample a solution containing both acid glycol at optimum molar ratio total chelate metals (0.5–1.0) yields best results. Regenerated thus enable production ultralow sulfur fuels (10 ppm) initial temperature 10–15°C lower their 3–4°C catalysts.
springer.com
sci-hub.se 参考文章(20)
A.V. Pashigreva, O.V. Klimov, G.A. Bukhtiyarova, M.A. Fedotov, D.I. Kochubey, Yu.A. Chesalov, V.I. Zaikovskii, I.P. Prosvirin, A.S. Noskov, The superior activity of the CoMo hydrotreating catalysts, prepared using citric acid: what's the reason? Studies in Surface Science and Catalysis. ,vol. 175, pp. 109- 116 ,(2010) , 10.1016/S0167-2991(10)75014-X
Jean Mazurelle, Carole Lamonier, Christine Lancelot, Edmond Payen, Christophe Pichon, Denis Guillaume, Use of the cobalt salt of the heteropolyanion [Co2Mo10O38H4]6- for the preparation of CoMo HDS catalysts supported on Al2O3, TiO2 and ZrO2 Catalysis Today. ,vol. 130, pp. 41- 49 ,(2008) , 10.1016/J.CATTOD.2007.07.008
Oleg V. Klimov, Anastasiya V. Pashigreva, Galina A. Bukhtiyarova, Sergey V. Budukva, Martin A. Fedotov, Dmitri I. Kochubey, Yuri A. Chesalov, Vladimir I. Zaikovskii, Alexandr S. Noskov, Bimetallic Co–Mo complexes: A starting material for high active hydrodesulfurization catalysts Catalysis Today. ,vol. 150, pp. 196- 206 ,(2010) , 10.1016/J.CATTOD.2009.07.095
M.A. Lélias, E. Le Guludec, L. Mariey, J. van Gestel, A. Travert, L. Oliviero, F. Maugé, Effect of EDTA addition on the structure and activity of the active phase of cobalt–molybdenum sulfide hydrotreatment catalysts Catalysis Today. ,vol. 150, pp. 179- 185 ,(2010) , 10.1016/J.CATTOD.2009.07.107
Pierre Dufresne, Hydroprocessing catalysts regeneration and recycling Applied Catalysis A-general. ,vol. 322, pp. 67- 75 ,(2007) , 10.1016/J.APCATA.2007.01.013
Victor Costa, Karin Marchand, Mathieu Digne, Christophe Geantet, New insights into the role of glycol-based additives in the improvement of hydrotreatment catalyst performances Catalysis Today. ,vol. 130, pp. 69- 74 ,(2008) , 10.1016/J.CATTOD.2007.05.013
Ksenia A. Leonova, Oleg V. Klimov, Dmitri I. Kochubey, Yuri A. Chesalov, Igor P. Prosvirin, Tatyana V. Larina, Alexandr S. Noskov, Synthesis and characterisation of Co–Mo complexes containing the [Co(C2H8N2)3]2+ cation and [Mo2O7L]4− anion, where L is an oxalic, tartaric, citric or nitrilotriacetic acid residue Polyhedron. ,vol. 47, pp. 65- 72 ,(2012) , 10.1016/J.POLY.2012.08.025
Miguel Ángel Calderón-Magdaleno, Juan Arturo Mendoza-Nieto, Tatiana E. Klimova, Effect of the amount of citric acid used in the preparation of NiMo/SBA-15 catalysts on their performance in HDS of dibenzothiophene-type compounds Catalysis Today. ,vol. 220, pp. 78- 88 ,(2014) , 10.1016/J.CATTOD.2013.06.002
Tatiana E. Klimova, Diego Valencia, Juan Arturo Mendoza-Nieto, Patricia Hernández-Hipólito, Behavior of NiMo/SBA-15 catalysts prepared with citric acid in simultaneous hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene Journal of Catalysis. ,vol. 304, pp. 29- 46 ,(2013) , 10.1016/J.JCAT.2013.03.027
A.V. Pashigreva, G.A. Bukhtiyarova, O.V. Klimov, Yu.A. Chesalov, G.S. Litvak, A.S. Noskov, Activity and sulfidation behavior of the CoMo/Al2O3 hydrotreating catalyst: The effect of drying conditions Catalysis Today. ,vol. 149, pp. 19- 27 ,(2010) , 10.1016/J.CATTOD.2009.07.096