A novel synthesis of CdSe nanocrystals

作者: Mauro Epifani , Cinzia Giannini , Liberato Manna

DOI: 10.1016/J.MATLET.2004.02.024

关键词:

摘要: Abstract A novel synthesis of CdSe nanocrystals is presented, which based on the room temperature reaction between selenourea and cadmium nitrate triggered by fast injection a base. long-chain thiol was employed for terminating aggregation species created reaction, obtaining monodispersed particles that were heat-treated in pyridine at 145 °C to grow larger particles. TEM observations optical absorption spectra indicate particle size depends parameters, while XRD shows formation with hexagonal crystal system. The analysis allows proposing first, simple model growth nanocrystals. mechanism seems proceed through cadmium–selenourea intermediate species.

参考文章(14)
Yan Li, Fuzhi Huang, Qingmin Zhang, Zhennan Gu, Solvothermal synthesis of nanocrystalline cadmium sulfide Journal of Materials Science. ,vol. 35, pp. 5933- 5937 ,(2000) , 10.1023/A:1026714004563
R. C. Kainthla, D. K. Pandya, K. L. Chopra, Structural and Optical Properties of Solution Grown CdSe 1 - x S x Films Journal of The Electrochemical Society. ,vol. 129, pp. 99- 102 ,(1982) , 10.1149/1.2123800
Raúl Ortega‐Borges, Daniel Lincot, Mechanism of Chemical Bath Deposition of Cadmium Sulfide Thin Films in the Ammonia‐Thiourea System In Situ Kinetic Study and Modelization Journal of The Electrochemical Society. ,vol. 140, pp. 3464- 3473 ,(1993) , 10.1149/1.2221111
Manoj Nirmal, Louis Brus, Luminescence Photophysics in Semiconductor Nanocrystals Accounts of Chemical Research. ,vol. 32, pp. 407- 414 ,(1999) , 10.1021/AR9700320
M. Kostoglou, N. Andritsos, A. J. Karabelas, Modeling Thin Film CdS Development in a Chemical Bath Deposition Process Industrial & Engineering Chemistry Research. ,vol. 39, pp. 3272- 3283 ,(2000) , 10.1021/IE990472Q
Peter C. Rieke, Susan B. Bentjen, Deposition of cadmium sulfide films by decomposition of thiourea in basic solutions Chemistry of Materials. ,vol. 5, pp. 43- 53 ,(1993) , 10.1021/CM00025A012
S.N. Sahu, Chemical deposition of CdS films: structure, RBS, PIXE, optical and photoelectrochemical solar cell studies Journal of Materials Science: Materials in Electronics. ,vol. 6, pp. 43- 51 ,(1995) , 10.1007/BF00208133
C. B. Murray, C. R. Kagan, M. G. Bawendi, Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies Annual Review of Materials Science. ,vol. 30, pp. 545- 610 ,(2000) , 10.1146/ANNUREV.MATSCI.30.1.545
César A. Estrada, P. K. Nair, M. T. S. Nair, Ralph A. Zingaro, Edward A. Meyers, Chemical Bath Deposition of ZnSe and CuSe Thin Films Using N,N‐Dimethylselenourea Journal of The Electrochemical Society. ,vol. 141, pp. 802- 806 ,(1994) , 10.1149/1.2054814