Silver(I)−Thiophene π Interaction in the Assembly of Coordination Networks with the Supramolecular Synthons R−C⋮C⊃Agn (R = 2- or 3-thienyl; n = 4)†
作者： Liang Zhao , Thomas C. W. Mak
DOI: 10.1021/OM700370P
关键词:
摘要: Silver−thiophene π interactions in two bonding modes, namely, η2-(CC) and κ-(C,S), have been observed for the first time crystalline silver(I) complexes (C4H3S-2)C⋮CAg·4AgCF3CO2 (1), 2[(C4H3S-2)C⋮CAg]·8AgCF3CO2·CH3CN (2), (C4H3S-3)C⋮CAg·4AgCF3CO2 (4), bearing thiophene ligands with an ethynide substituent at 2- or 3-position. Introduction of additional betaine component 3[(C4H3S-2)C⋮CAg]·8AgCF3CO2·Me3N+CH2CO2-·4.5H2O (3) replacement trifluoroacetate by pentafluoropropionate (C4H3S-3)C⋮CAg·5AgC2F5CO2·4H2O (5) were found to interrupt these silver−thiophene instead form infinite π−π-stacked silver chain a π−π-stacking-stabilized Ag8 aggregate, respectively. The establishment new kind silver−ethynide supramolecular synthon, R−C⋮C⊃Agn (R = 2-, 3-thienyl; n 4), highlights potential building metal−organic frameworks utilizing π-coordination capacity heterocyclic ring.
acs.org
sci-hub.se 参考文章(22)
Pekka Pyykkö, Strong Closed-Shell Interactions in Inorganic Chemistry. Chemical Reviews. ,vol. 97, pp. 597- 636 ,(1997) , 10.1021/CR940396V
Daisuke Yamazaki, Tohru Nishinaga, Nobuhide Tanino, Koichi Komatsu, Terthiophene Radical Cations End-Capped by Bicyclo[2.2.2]octene Units: Formation of Bent π-Dimers Mutually Attracted at the Central Position Journal of the American Chemical Society. ,vol. 128, pp. 14470- 14471 ,(2006) , 10.1021/JA065995L
Andrea Bencini, Antonio Bianchi, Paolo Dapporto, Enrique Garcia-Espana, Mauro Micheloni, Piero Paoletti, Polynuclear zinc(II) complexes with large polyazacycloalkanes. 2. Equilibrium studies and crystal structure of the binuclear complex [Zn2LCl2](Cl)ClO4.cntdot.H2O (L = 1,4,7,10,13,16,19,22-octaazacyclotetracosane) Inorganic Chemistry. ,vol. 28, pp. 1188- 1191 ,(1989) , 10.1021/IC00305A033
Jaume Veciana, Concepcio Rovira, Maria I. Crespo, Olga Armet, Victor M. Domingo, Fernando Palacio, Stable polyradicals with high-spin ground states. 1. Synthesis, separation, and magnetic characterization of the stereoisomers of 2,4,5,6-tetrachloro-.alpha.,.alpha.,.alpha.',.alpha.'-tetrakis(pentachlorophenyl)-m-xylylene biradical Journal of the American Chemical Society. ,vol. 113, pp. 2552- 2561 ,(1991) , 10.1021/JA00007A033
Nicholas C. Payne, Ravindranath Ramachandran, Ilse Treurnicht, Richard J. Puddephatt, Easy double metalation of a diphosphinomethane ligand: structure of the remarkable octagold cage complex [Au8Cl2{.mu.3-(MeO)2PCHP(OMe)2}2{.mu.4-(MeO)2PCP(OMe)2}2].cntdot.CHCl3 Organometallics. ,vol. 9, pp. 880- 882 ,(1990) , 10.1021/OM00117A062
Stéphanie N. Ringelberg, Auke Meetsma, Bart Hessen, Jan H. Teuben, Thiophene C−H Activation as a Chain-Transfer Mechanism in Ethylene Polymerization: Catalytic Formation of Thienyl-Capped Polyethylene† Journal of the American Chemical Society. ,vol. 121, pp. 6082- 6083 ,(1999) , 10.1021/JA984288S
W. Dean Harman, David A. Delafuente, William H. Myers, Michal Sabat, Tungsten(0)η2-Thiophene Complexes: Dearomatization of Thiophene and Its Facile Oxidation, Protonation, and Hydrogenation Organometallics. ,vol. 24, pp. 1876- 1885 ,(2005) , 10.1021/OM050050I
Hisashi Konaka, Liang Ping Wu, Megumu Munakata, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, Syntheses and Structures of Photochromic Silver(I) Coordination Polymers withcis-1,2-Dicyano-1,2-bis(2,4,5-trimethyl-3-thienyl)ethene Inorganic Chemistry. ,vol. 42, pp. 1928- 1934 ,(2003) , 10.1021/IC020525N
Jih Ru Hwu, Paul S. Furth, Silicon-directed decarbonylation of trimethylsilyl .beta.,.gamma.-enals by photolysis Journal of the American Chemical Society. ,vol. 111, pp. 8834- 8841 ,(1989) , 10.1021/JA00206A011
A. Bondi, van der Waals Volumes and Radii The Journal of Physical Chemistry. ,vol. 68, pp. 441- 451 ,(1964) , 10.1021/J100785A001