THE CHEMISTRY OF METAL CARBONATO AND CARBON DIOXIDE COMPLEXES

摘要: In order to provide some background for subsequent sections in this review, the physical properties, aqueous equilibria, and kinetics of CO2 (aq) its hydrolysis products are discussed briefly. The procedures preparation metal carbonato complexes, their spectral characteristics, x-ray crystallographic structures tabulated. Solid-state thermal reactions producing certain complexes discussed. equilibrium section article serves mainly list current values stability constants, ion-pair formation constants solubility data, related thermodynamic data complexes. on is composed a detailed discussion individual modes reaction with present-day concepts mechanisms involved these processes how each type can be correlated. material relatively new field involving metal-carbon dioxide divided into three sections. These include characterization metal-CO2 species fixation insertion reactions. review concluded applied geochemistry, oceanography, biochemistry, which meant give research chemists insight aspects implications chemistry areas.more » 628 references, 9 figures, 41 tables.« less