Formation of luminescent terbium(III) self-assemblies from pyridyl bis-amidothioureas based ligands in MeOH and in water-DMSO solutions and their use in anion sensing application.

作者: Christophe Lincheneau , Rebecca M. Duke , Thorfinnur Gunnlaugsson

DOI: 10.1039/C2OB25720C

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摘要: The self-assembly between the amidothiourea ligands 1 and 2 Tb(III) gave rise to formation of 1 : 1 3 : 1 (ligand–Tb) supramolecular architectures that were shown be luminescent in both MeOH water–DMSO solutions; preliminary investigations latter system also showed their emission was modulated upon interacting with anions such as acetate phosphate due host–guest formation.

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