Experimental evidence and bond characterization of a cyclopropenylgermylene
作者： Shinobu Tsutsui , Hiromasa Tanaka , Eunsang Kwon , Shigeki Matsumoto , Kenkichi Sakamoto
DOI: 10.1016/J.JORGANCHEM.2005.09.041
关键词:
摘要: Abstract The reduction of p -anisyl(1,2,3-tri- tert -butylcycloprop-2-en-1-yl)dichlorogermane ( 1 ) with potassium in the presence an excess -butyldimethylsilane benzene under reflux gave -anisyl( -butyldimethylsilyl)(1,2,3-tri- -butylcycloprop-2-en-1-yl)germane 4 15% yield. formation indicates that -butylcycloprop-2-en-1-yl)germylene 2 ), which is first example a (cycloprop-2-en-1-yl)germylene derivative, was generated and trapped by hydrosilane. DFT calculations revealed cis -2- -anisyl-1,3,4-tri- -butyl-2-germabicyclo[1.1.0]butane-2,4-diyl structure - 5 8.0 kJ/mol more stable than . NBO analysis has 2-germabicyclo[1.1.0]butane diradical character.
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sci-hub.se 参考文章(44)
The chemistry of the cyclopropyl group Wiley. ,(1995) , 10.1002/0470023481
Joseph J. Gajewski, Hydrocarbon thermal isomerizations ,(1981)
Yoshihiro Kon, Kenkichi Sakamoto, Chizuko Kabuto, Mitsuo Kira, A Cobalt Silacyclobutadiene Complex Organometallics. ,vol. 24, pp. 1407- 1409 ,(2005) , 10.1021/OM0490029
Hideki Sakurai, Kenkichi Sakamoto, Mitsuo Kira, PHOTOCHEMISTRY OF DIBENZO-1,1,2,2,3,3 -HEXAMETHYL-1,2,3-TRISILACYCLOHEPTA-4,6-DIENE AND THE GERMANIUM ANALOG. GENERATION OF TETRAMETHYLDISILENE BY FREE-RADICAL DISPROPORTIONATION AND THE FIRST SPECTROSCOPIC DETECTION OF DIMETHYLGERMYLENE Chemistry Letters. ,vol. 13, pp. 1379- 1382 ,(1984) , 10.1246/CL.1984.1379
Hiromasa Tanaka, Eunsang Kwon, Shinobu Tsutsui, Shigeki Matsumoto, Kenkichi Sakamoto, Relationship between the molecular structure and the π-π* transition energy of a lattice-framework disilene: A DFT study European Journal of Inorganic Chemistry. ,vol. 2005, pp. 1235- 1237 ,(2005) , 10.1002/EJIC.200400942
Peter Jutzi, Holger Schmidt, Beate Neumann, Hans-Georg Stammler, Bis(2,4,6-tri-tert-butylphenyl)germylene Reinvestigated: Crystal Structure, Lewis Acid Catalyzed C−H Insertion, and Oxidation to an Unstable Germanone Organometallics. ,vol. 15, pp. 741- 746 ,(1996) , 10.1021/OM950558T
Tamás Veszprémi, Masae Takahashi, Jun Ogasawara, Kenkichi Sakamoto, Mitsuo Kira, AN AB INITIO MO STUDY OF STRUCTURE AND REACTIVITY OF 4-SILATRIAFULVENE Journal of the American Chemical Society. ,vol. 120, pp. 2408- 2414 ,(1998) , 10.1021/JA971925Q
Robin Walsh, Sven Untiedt, Armin De Meijere, Gas‐Phase Kinetics of the Pyrolysis of Some 3,3‐Dimethyl‐1‐(trimethylsilyl)‐cyclopropenes — Unexpected Product Distribution in the Cyclopropene Rearrangement Chemische Berichte. ,vol. 127, pp. 237- 245 ,(1994) , 10.1002/CBER.19941270134
Omar W. Steward, Joseph E. Dziedzic, James S. Johnson, Carboxysilanes and -germanes. II. Synthesis and spectral properties of triorganosilane- and triorganogermanecarboxylic acid Journal of Organic Chemistry. ,vol. 36, pp. 3475- 3480 ,(1971) , 10.1021/JO00822A001
Dhananjay B. Puranik, M. Pontier. Johnson, Mark J. Fink, Synthesis and solid-state structures of some sterically hindered cyclopropenylsilanes Organometallics. ,vol. 8, pp. 770- 777 ,(1989) , 10.1021/OM00105A030