The complex nonstoichiometry of wüstite Fe1-zO: Review and comments
作者： Jean-Raymond Gavarri , Claude Carel
DOI: 10.1016/J.PROGSOLIDSTCHEM.2018.10.001
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摘要: Abstract Thermodynamic properties and structural aspects of the nonstoichiometric wustite Fe1-zO, its modifications - so-called pseudo-phases as functions departure z from stoichiometry equilibrium temperature are reviewed 1960 to present. The complexity phase diagram is described in some details. first order transition W ⇆ W′ specified on iron/wustite boundary near 1185 K. Transitions correlated Wi at T(W) > 1185 K W'j T(W′)
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