Photofunctionalization of EB-PVD HA-coated nano-pore surface of Ti–30Nb–xZr alloy for dental implants

作者: Han-Cheol Choe

DOI: 10.1016/J.SURFCOAT.2012.05.018

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摘要: Abstract In this study, photoelectrochemical analysis of bioactive material coated nanotubular surface Ti–30Nb–xZr alloy has been investigated using a potentiostat and Xenon lamp. Ternary Ti–30Nb–xZr(x = 3, 15 wt.%) alloys were prepared, nanotube was formed in 1 M H3PO4 + NaF(0.8 wt.%). Hydroxyapatite (HA) on by electron-beam physical vapor deposition (EB-PVD) method. The characteristics behavior FE-SEM, EDS, XRD potentiostat. microstructures the Ti–30Nb–3Zr Ti–30Nb–15Zr showed an equiaxed grain structure with needle-like α phase β grains. large nanotubes surrounded smaller diameter highly ordered alloy. HA irregular flake-like particles (211) (112) crystalline planes. UV-irradiated alloy, current density passive region higher than that non-UV-irradiated whereas for difference between not significant. Rp value coated/nanotube under UV-irradiation other surface. angle close to 60–70°. study suggested photofunctionalization reaction strongly depends oxide surface, crystallinity hydroxyapatite alloying elements.

参考文章(14)
Yong-Hoon Jeong, Han-Cheol Choe, Sang-Won Eun, Hydroxyapatite coating on the Ti–35Nb–xZr alloy by electron beam-physical vapor deposition Thin Solid Films. ,vol. 519, pp. 7050- 7056 ,(2011) , 10.1016/J.TSF.2011.04.086
Hideki Aita, Wael Att, Takeshi Ueno, Masahiro Yamada, Norio Hori, Fuminori Iwasa, Naoki Tsukimura, Takahiro Ogawa, Ultraviolet light-mediated photofunctionalization of titanium to promote human mesenchymal stem cell migration, attachment, proliferation and differentiation. Acta Biomaterialia. ,vol. 5, pp. 3247- 3257 ,(2009) , 10.1016/J.ACTBIO.2009.04.022
Kang Lee, Han-Cheol Choe, Byung-Hoon Kim, Yeong-Mu Ko, The biocompatibility of HA thin films deposition on anodized titanium alloys Surface & Coatings Technology. ,vol. 205, ,(2010) , 10.1016/J.SURFCOAT.2010.08.015
Thomas J Webster, Celaletdin Ergun, Robert H Doremus, Richard W Siegel, Rena Bizios, Enhanced functions of osteoblasts on nanophase ceramics Biomaterials. ,vol. 21, pp. 1803- 1810 ,(2000) , 10.1016/S0142-9612(00)00075-2
Han-Cheol Choe, Won-Gi Kim, Yong-Hoon Jeong, Surface characteristics of HA coated Ti-30Ta-xZr and Ti-30Nb-xZr alloys after nanotube formation Surface & Coatings Technology. ,vol. 205, ,(2010) , 10.1016/J.SURFCOAT.2010.08.020
Hiroaki Tsuchiya, Jan M. Macak, Andrei Ghicov, Luciano Taveira, Patrik Schmuki, Self-organized porous TiO2 and ZrO2 produced by anodization Corrosion Science. ,vol. 47, pp. 3324- 3335 ,(2005) , 10.1016/J.CORSCI.2005.05.041
Viswanathan S. Saji, Han Cheol Choe, William A. Brantley, An electrochemical study on self-ordered nanoporous and nanotubular oxide on Ti-35Nb-5Ta-7Zr alloy for biomedical applications. Acta Biomaterialia. ,vol. 5, pp. 2303- 2310 ,(2009) , 10.1016/J.ACTBIO.2009.02.017
Viswanathan S. Saji, Han Cheol Choe, Electrochemical corrosion behaviour of nanotubular Ti–13Nb–13Zr alloy in Ringer’s solution Corrosion Science. ,vol. 51, pp. 1658- 1663 ,(2009) , 10.1016/J.CORSCI.2009.04.013