Fabrication of composite microstructures by capillarity-driven wetting of aligned carbon nanotubes with polymers

作者: E J García , A J Hart , B L Wardle , A H Slocum

DOI: 10.1088/0957-4484/18/16/165602

关键词:

摘要: The interaction, or wetting, of long aligned carbon nanotube (CNT) forests with off-the-shelf (no solvent added) commercial thermoset polymers is investigated experimentally. A technique for creating vertically CNT composite microstructures various shapes presented. effective wetting the forests, as evidenced by a lack voids, three widely varying viscosities supports feasibility using in large-scale hybrid advanced architectures. Among routes identified polymer to penetrate forest, capillarity-driven along axis preferred route. Aligned are useful many applications including test structures direct mechanical and multifunctional property characterization CNT?polymer materials.

参考文章(18)
Bruce J Hinds, Nitin Chopra, Terry Rantell, Rodney Andrews, Vasilis Gavalas, Leonidas G Bachas, Aligned multiwalled carbon nanotube membranes. Science. ,vol. 303, pp. 62- 65 ,(2004) , 10.1126/SCIENCE.1092048
B. Safadi, R. Andrews, E. A. Grulke, MULTIWALLED CARBON NANOTUBE POLYMER COMPOSITES: SYNTHESIS AND CHARACTERIZATION OF THIN FILMS Journal of Applied Polymer Science. ,vol. 84, pp. 2660- 2669 ,(2002) , 10.1002/APP.10436
Florian H. Gojny, Karl Schulte, Functionalisation effect on the thermo-mechanical behaviour of multi-wall carbon nanotube/epoxy-composites Composites Science and Technology. ,vol. 64, pp. 2303- 2308 ,(2004) , 10.1016/J.COMPSCITECH.2004.01.024
N. Chakrapani, B. Wei, A. Carrillo, P. M. Ajayan, R. S. Kane, Capillarity-driven assembly of two-dimensional cellular carbon nanotube foams Proceedings of the National Academy of Sciences of the United States of America. ,vol. 101, pp. 4009- 4012 ,(2004) , 10.1073/PNAS.0400734101
J Sandler, M.S.P Shaffer, T Prasse, W Bauhofer, K Schulte, A.H Windle, Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties Polymer. ,vol. 40, pp. 5967- 5971 ,(1999) , 10.1016/S0032-3861(99)00166-4
Florian H Gojny, Jacek Nastalczyk, Zbigniew Roslaniec, Karl Schulte, Surface modified multi-walled carbon nanotubes in CNT/epoxy-composites Chemical Physics Letters. ,vol. 370, pp. 820- 824 ,(2003) , 10.1016/S0009-2614(03)00187-8
Erik T Thostenson, Zhifeng Ren, Tsu-Wei Chou, Advances in the science and technology of carbon nanotubes and their composites: a review Composites Science and Technology. ,vol. 61, pp. 1899- 1912 ,(2001) , 10.1016/S0266-3538(01)00094-X
M.C. Paiva, B. Zhou, K.A.S. Fernando, Y. Lin, J.M. Kennedy, Y.-P. Sun, Mechanical and morphological characterization of polymer–carbon nanocomposites from functionalized carbon nanotubes Carbon. ,vol. 42, pp. 2849- 2854 ,(2004) , 10.1016/J.CARBON.2004.06.031
Anastasios John Hart, Alexander H. Slocum, Rapid growth and flow-mediated nucleation of millimeter-scale aligned carbon nanotube structures from a thin-film catalyst. Journal of Physical Chemistry B. ,vol. 110, pp. 8250- 8257 ,(2006) , 10.1021/JP055498B