Selective, tunable O2 binding in cobalt(II)–triazolate/pyrazolate metal–organic frameworks

作者: Dianne J. Xiao , Miguel I. Gonzalez , Lucy E. Darago , Konstantinos D. Vogiatzis , Emmanuel Haldoupis

DOI: 10.1021/JACS.6B03680

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摘要: … (30) On the other hand, it has been shown that the intermediate basicity of triazolates allows the iron(II) centers in Fe-BTTri to convert between high-spin and low-spin configurations, …

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