Reactivite d'hydrocarbures methylenecyclo-hexaniques—I
作者： D. Jasserand , J.P. Girard , J.C. Rossi , R. Granger
DOI: 10.1016/0040-4020(76)85209-X
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摘要: Resume Les methylenecyclohexanes diversement substitues, prepares avec d'excellents rendements par les reactions de Corey et Chaykovsky puis Cornforth, donnent preferentiellement alcools tertiaires resultant d'une attaque axiale du solvant suivant l'oxymercuration-demercuration. L'attaque a lieu en trans rapport au substituant lorsque dernier est position 2. Avec substitues α la double liaison un groupe hydroxy ou methoxy resultats sont identiques. Pour composes acetoxyles, cis obtenus intramoleculaire acetoxyle sur l'ion mercurinium intermediaire. facteurs influencant stereochimie des interactions courte distance.
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