The microwave spectrum of the FO2 radical
作者： Marcel Bogey , Paul B. Davies , Claire Demuynck , Jean Luc Destombes , Trevor J. Sears
DOI: 10.1080/00268978900101611
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摘要: Over 250 mm wave transitions of FO2 in its ground 2 A″ vibronic state have been detected using the F + O2 M reaction as a source radical. The lines assigned to a-type involving levels with N between 7 and 15 show resolved or partially fine structure hyperfine structure. A combined fit 445 infrared combination differences yielded rotation, distortion, spin-rotation parameters. tensor components that were determined used derive more accurate parameters for several vibrationally excited levels, based on spin splittings from previously published FTIR diode laser results. are quite good agreement with, much than, those earlier E.S.R. results FO2, when latter rotated into principal inertial axis system molecule.
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