Flexible Carbon Electrodes for Electrochemical Detection of Bisphenol-A, Hydroquinone and Catechol in Water Samples

作者: Acelino C. de Sá , Simone C. Barbosa , Paulo A. Raymundo-Pereira , Deivy Wilson , Flávio M. Shimizu

DOI: 10.3390/CHEMOSENSORS8040103

关键词:

摘要: The detection of pollutant traces in the public water supply and aquifers is essential for safety population. In this article, we demonstrate that a simple electrochemical procedure acidic solution can be employed enhancing sensitivity flexible screen-printed carbon electrodes (SPEs) to detect bisphenol-A (BPA), hydroquinone, catechol, simultaneously. SPEs were pretreated electrochemically H2SO4 solution, which did not affect their morphology, yielding high current signals with well separated oxidation peaks. values 0.28, 0.230, 0.056 µA L µmol−1 limits 0.12, 0.82, 0.95 µmol L−1 BPA, respectively. sensors reproducible selective detecting BPA plastic cups, adequate specificity affected by interferents from samples. simple, inexpensive, SPE may thus used emerging pollutants monitor quality.

参考文章(37)
S.A.S. Canevari, T.C., Raymundo-Pereira, P.A., Landers, R., Machado, Direct Synthesis of Ag Nanoparticles Incorporated on a Mesoporous Hybrid Material as a Sensitive Sensor for the Simultaneous Determination of Dihydroxybenzenes Isomers European Journal of Inorganic Chemistry. ,vol. 2013, pp. 5746- 5754 ,(2013) , 10.1002/EJIC.201300879
KV Ragavan, Navin K Rastogi, MS Thakur, None, Sensors and biosensors for analysis of bisphenol-A Trends in Analytical Chemistry. ,vol. 52, pp. 248- 260 ,(2013) , 10.1016/J.TRAC.2013.09.006
Jianying Hu, Shuijie Cheng, Takako Aizawa, Yoshiyasu Terao, Shoichi Kunikane, Products of Aqueous Chlorination of 17β-Estradiol and Their Estrogenic Activities Environmental Science & Technology. ,vol. 37, pp. 5665- 5670 ,(2003) , 10.1021/ES034324+
Xiaolan Chen, Can Wang, Xinmei Tan, Jianxiu Wang, Determination of bisphenol A in water via inhibition of silver nanoparticles-enhanced chemiluminescence. Analytica Chimica Acta. ,vol. 689, pp. 92- 96 ,(2011) , 10.1016/J.ACA.2011.01.031
S.A.S. Canevari, T.C., Raymundo-Pereira, P.A., Landers, R., Benvenutti, E.V., Machado, Sol-gel thin-film based mesoporous silica and carbon nanotubes for the determination of dopamine, uric acid and paracetamol in urine Talanta. ,vol. 116, pp. 726- 735 ,(2013) , 10.1016/J.TALANTA.2013.07.044
N. Olea, J. P. Arrebola, J. Taoufiki, R. Fernández-Valades, R. Prada, N. Navea, J. M. Molina-Molina, M. F. Fernandez, Alkylphenols and bisphenol-A and its chlorinated derivatives in adipose tissue of children. Environmental Toxicology. ,vol. 110, pp. 129- 138 ,(2008) , 10.2495/ETOX080141
Stephanie Vandentorren, Florence Zeman, Lise Morin, Hélène Sarter, Marie-Laure Bidondo, Amivi Oleko, Henri Leridon, Bisphenol-A and phthalates contamination of urine samples by catheters in the Elfe pilot study : implications for large-scale biomonitoring studies Environmental Research. ,vol. 111, pp. 761- 764 ,(2011) , 10.1016/J.ENVRES.2011.05.018
Xiuli Niu, Wu Yang, Guoying Wang, Jie Ren, Hao Guo, Jinzhang Gao, A novel electrochemical sensor of bisphenol A based on stacked graphene nanofibers/gold nanoparticles composite modified glassy carbon electrode Electrochimica Acta. ,vol. 98, pp. 167- 175 ,(2013) , 10.1016/J.ELECTACTA.2013.03.064
Thabile Ndlovu, Omotayo A. Arotiba, Srinivasan Sampath, Rui W. Krause, Bhekie B. Mamba, An Exfoliated Graphite-Based Bisphenol A Electrochemical Sensor Sensors. ,vol. 12, pp. 11601- 11611 ,(2012) , 10.3390/S120911601