Synthesis of a phthalonitrile derivative of fullerenopyrrolidine
作者： N. L. Bazyakina , O. N. Suvorova , K. N. Maksimova
DOI: 10.1007/S11172-009-0071-X
关键词:
摘要: Interest in the photophysical properties of fullerene derivatives is based on rather easy excitation (acceptor)—linkage—electron donor systems producing states with charge separation. The lifetime excited state can vary a wide range depending type functional groups and second component.1,2 Fullerene—phthalocyanine supramolecular which strong acceptor interactions result long lived separation are intensively used now.3—6 Reactions cycloaddition formylphthalocyanines to mainly for preparation this type.4 purpose work synthesize con taining phthalonitrile further formation containing phthalocyanine macrocycle. 2 [4 (3,4 Dicyanophenoxy)phenyl] N methyl 3,4 fullerenopyrrolidine was synthesized by 1,3 dipolar reaction C60 azomethine
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