Zeeman spectra of the à 1Au←X̃ 1Ag transition of trans-glyoxal studied by Doppler-free two-photon fluorescence excitation spectroscopy
作者： Masatoshi Misono , Jin Guo Wang , Hajime Katô , Masaaki Baba
DOI: 10.1063/1.1554734
关键词:
摘要: Doppler-free two-photon fluorescence excitation spectra of the A 1Au(v7′=1)←X 1Ag(v″=0) transition trans-glyoxal were measured by propagating a laser beam either polarized parallel (π pump) or perpendicular (σ to magnetic field 6 T. π pump and σ dependence Zeeman Q(K)Q(J=6) lines for K=0–6 was measured. Intensities components Q(6)Q(6) observed have maxima at high low wave number ends minimum middle pump, minima maximum pump. By comparing calculated patterns spectra, it became clear that tensor M00 is dominant effective intermediate state 1 1Bu(ππ*). K Q(K)Q(J=15) measured, splittings increase proportionally K2. J Q(K=J)Q(J) J=...
harvard.edu
scitation.org
aip.org
sci-hub.se 参考文章(21)
Masatoshi Misono, Jinguo Wang, Miho Ushino, Mitsushi Okubo, Hajime Katô, Masaaki Baba, Saburo Nagakura, Doppler-free two-photon absorption spectroscopy and the Zeeman effect of the A [sup 1]B[sub 2u]←X [sup 1]A[sub 1g]14[sub 0][sup 1]1[sub 0][sup 1] band of benzene The Journal of Chemical Physics. ,vol. 116, pp. 162- 171 ,(2002) , 10.1063/1.1421069
Hajime Katô, Takuya Oonishi, Kiyoshi Nishizawa, Shunji Kasahara, Masaaki Baba, Doppler-free two-photon absorption spectroscopy of the A1Au←X1Ag transition of trans-glyoxal Journal of Chemical Physics. ,vol. 106, pp. 8392- 8400 ,(1997) , 10.1063/1.473922
Hajime Katô, Katsuhiro Sawa, Hiroyuki Kuwano, Shunji Kasahara, Masaaki Baba, Saburo Nagakura, Ultrahigh-resolution spectroscopy of the A1Au←X1Ag transition of trans-glyoxal Journal of Chemical Physics. ,vol. 109, pp. 4798- 4806 ,(1998) , 10.1063/1.477017
G. Placzek, E. Teller, Die Rotationsstruktur der Ramanbanden mehratomiger Moleküle European Physical Journal. ,vol. 81, pp. 209- 258 ,(1933) , 10.1007/BF01338366
Jon T. Hougen, Theoretical Interpretation of the Zeeman Effect in the Near‐Ultraviolet Bands of CS2 Journal of Chemical Physics. ,vol. 41, pp. 363- 366 ,(1964) , 10.1063/1.1725875
Theodor W. Hänsch, Arthur L. Schawlow, George W. Series, The Spectrum of Atomic Hydrogen Scientific American. ,vol. 240, pp. 94- 111 ,(1979) , 10.1038/SCIENTIFICAMERICAN0379-94
Dmitri G. Fedorov, Shiro Koseki, Michael W. Schmidt, Mark S. Gordon, Spin-orbit coupling in molecules: Chemistry beyond the adiabatic approximation International Reviews in Physical Chemistry. ,vol. 22, pp. 551- 592 ,(2003) , 10.1080/0144235032000101743
Jeffrey F. Gaw, Henry F. Schaefer, Molecular structures and energetics for the lowest triplet states of glyoxal Journal of Chemical Physics. ,vol. 83, pp. 1741- 1745 ,(1985) , 10.1063/1.449361
Kuo-mei Chen, Edward S. Yeung, Rovibronic two-photon transitions of symmetric top molecules Journal of Chemical Physics. ,vol. 69, pp. 43- 52 ,(1978) , 10.1063/1.436373
D.A Ramsay, M Vervloet, F Vanhorenbeke, M Godefroid, M Herman, Rotational analysis of the 0-0 band of the ã3Au-X̃1Ag system of trans-glyoxal Journal of Molecular Spectroscopy. ,vol. 149, pp. 348- 355 ,(1991) , 10.1016/0022-2852(91)90291-H