Transesterification of palm oil on KyMg1 − xZn1 + xO3 catalyst: Effect of Mg–Zn interaction

作者: M.A. Olutoye , B.H. Hameed

DOI: 10.1016/J.FUPROC.2010.01.014

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摘要: Abstract The Mg–Zn interaction effect of KyMg1 − xZn1 + xO3 heterogeneous type catalyst and its performance on transesterification palm oil have been studied using the response surface methodology factorial design experiments. was synthesized co-precipitation method activity assessed by into fatty acid methyl esters. ratio Mg/Zn metal interaction, temperature time calcination were found to positive influence conversion ester (FAME) with being more significant. catalytic decrease at higher K2Mg0.34Zn1.66O3 4.81 gave FAME content 73% a loading 1.404 wt.% molar methanol 6:1 150 °C in 6 h. A regression model obtained predict conversions esters as function ratio, time. observed due synergetic structure composition.

参考文章(40)
Yoshitake Hasegawa, Masaaki Haneda, Yoshiaki Kintaichi, Hideaki Hamada, Zn-promoted Rh/SiO2 catalyst for the selective reduction of NO with H2 in the presence of O2 and SO2 Applied Catalysis B-environmental. ,vol. 60, pp. 41- 47 ,(2005) , 10.1016/J.APCATB.2005.02.020
Jon H. Van Gerpen, Earl G. Hammond, Liangping Yu, Abdul Monyem, Determining the Influence of Contaminants on Biodiesel Properties SAE Technical Paper Series. pp. 173- 190 ,(1997) , 10.4271/971685
C. Thiandoume, A. Lusson, P. Galtier, V. Sallet, Metal organic vapour phase epitaxy of MgO films grown on c-plane Sapphire Journal of Crystal Growth. ,vol. 311, pp. 4371- 4373 ,(2009) , 10.1016/J.JCRYSGRO.2009.07.019
Paresh Shimpi, Pu-Xian Gao, Daniel G Goberman, Yong Ding, Low temperature synthesis and characterization of MgO/ZnO composite nanowire arrays Nanotechnology. ,vol. 20, pp. 125608- ,(2009) , 10.1088/0957-4484/20/12/125608
Jennifer E. Readman, Ian Gameson, Joseph A. Hriljac, Paul A. Anderson, Observation of a rhombohedral phase change during the dehydration of zinc-exchanged zeolite A Microporous and Mesoporous Materials. ,vol. 86, pp. 96- 105 ,(2005) , 10.1016/J.MICROMESO.2005.06.038
Sanjib Kumar Karmee, Anju Chadha, Preparation of biodiesel from crude oil of Pongamia pinnata. Bioresource Technology. ,vol. 96, pp. 1425- 1429 ,(2005) , 10.1016/J.BIORTECH.2004.12.011
Katabathini Narasimha Rao, Adapa Sridhar, Adam F. Lee, Stewart J. Tavener, Nigel A. Young, Karen Wilson, Zirconium phosphate supported tungsten oxide solid acid catalysts for the esterification of palmitic acid Green Chemistry. ,vol. 8, pp. 790- 797 ,(2006) , 10.1039/B606088A
M. Muruganandham, J.J. Wu, Synthesis, characterization and catalytic activity of easily recyclable zinc oxide nanobundles Applied Catalysis B-environmental. ,vol. 80, pp. 32- 41 ,(2008) , 10.1016/J.APCATB.2007.11.006
Subramani Velu, Kenzi Suzuki, Munusamy Vijayaraj, Sanmitra Barman, Chinnakonda S. Gopinath, In situ XPS investigations of Cu1−xNixZnAl-mixed metal oxide catalysts used in the oxidative steam reforming of bio-ethanol Applied Catalysis B-environmental. ,vol. 55, pp. 287- 299 ,(2005) , 10.1016/J.APCATB.2004.09.007