A 3.6 V lithium-based fluorosulphate insertion positive electrode for lithium-ion batteries.
作者： N. Recham , J-N. Chotard , L. Dupont , C. Delacourt , W. Walker
DOI: 10.1038/NMAT2590
关键词:
摘要: Li-ion batteries have contributed to the commercial success of portable electronics, and are now in a position to influence higher-volume applications such as plug-in hybrid electric vehicles. Most commercial Li-ion batteries use positive electrodes based on lithium cobalt oxides. Despite showing a lower voltage than cobalt-based systems (3.45 V versus 4 V) and a lower energy density, LiFePO4 has emerged as a promising contender owing to the cost sensitivity of higher-volume markets. LiFePO4 also shows intrinsically low ionic and …
harvard.edu
nature.com
sci-hub.se 参考文章(26)
Guohua Li, Hideto Azuma, Masayuki Tohda, LiMnPO4 as the Cathode for Lithium Batteries Electrochemical and Solid State Letters. ,vol. 5, ,(2002) , 10.1149/1.1475195
P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J-M. Tarascon, Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries Nature. ,vol. 407, pp. 496- 499 ,(2000) , 10.1038/35035045
Yazid M. Saidi, Jeffrey L. Swoyer, Jeremy Barker, Lithium metal fluorophosphate materials and preparation thereof ,(2001)
Nathalie Ravet, Jean-Francois Magnan, Michel Gauthier, Michel Armand, Method for synthesis of carbon-coated redox materials with controlled size ,(2001)
Marc Doyle, John Newman, Jan Reimers, A quick method of measuring the capacity versus discharge rate for a dual lithium-ion insertion cell undergoing cycling Journal of Power Sources. ,vol. 52, pp. 211- 216 ,(1994) , 10.1016/0378-7753(94)02012-4
Yi-Xiao Li, Zheng-Liang Gong, Yong Yang, Synthesis and characterization of Li2MnSiO4/C nanocomposite cathode material for lithium ion batteries Journal of Power Sources. ,vol. 174, pp. 528- 532 ,(2007) , 10.1016/J.JPOWSOUR.2007.06.126
Juan Rodríguez-Carvajal, Recent advances in magnetic structure determination by neutron powder diffraction Physica B: Condensed Matter. ,vol. 192, pp. 55- 69 ,(1993) , 10.1016/0921-4526(93)90108-I
J. Barker, M. Y. Saidi, J. L. Swoyer, A Comparative Investigation of the Li Insertion Properties of the Novel Fluorophosphate Phases, NaVPO4 F and LiVPO4 F Journal of The Electrochemical Society. ,vol. 151, ,(2004) , 10.1149/1.1785796
A. K. Padhi, V. Manivannan, J. B. Goodenough, Tuning the Position of the Redox Couples in Materials with NASICON Structure by Anionic Substitution Journal of The Electrochemical Society. ,vol. 145, pp. 1518- 1520 ,(1998) , 10.1149/1.1838513
B. L. Ellis, W. R. M. Makahnouk, Y. Makimura, K. Toghill, L. F. Nazar, A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries Nature Materials. ,vol. 6, pp. 749- 753 ,(2007) , 10.1038/NMAT2007