Conformational Regulation and Crystalline Manipulation of PLLA through a Self-Assembly Nucleator
作者： Chunhai Li , Shanshan Luo , Jianfeng Wang , Hong Wu , Shaoyun Guo
DOI: 10.1021/ACS.BIOMAC.7B00367
关键词:
摘要: Self-assembly nucleators have been increasingly used to manipulate the crystallization of PLLA due to their strong intermolecular interaction with PLLA, while the molecular mechanism of such interaction is still unrevealed. In present work, one special self-assembly nucleator (TMC-300) with relatively high solubility in PLLA matrix, is chosen to investigate how the interaction works at molecular level to promote the crystallization of PLLA mainly through time-resolved spectroscopy. The results indicate that due to the dipole–dipole NH …
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