Enzymatic catalysis of the Diels-Alder reaction in the biosynthesis of natural products.
作者： Hideaki Oikawa , Tetsuo Tokiwano
DOI: 10.1039/B305068H
关键词:
摘要: Recent studies on enzymes catalyzing the Diels- Alder reaction. often named "Diels-Alderases", clearlydemonstrated involvement of this synthetically useful reaction in biosynthesis natural products.This review covers Diels-Alder type cycloadducts. synthetic efforts chemical feasibility ofthe biosynthctic Diels - and a brief history Diels-Alderases. In addition,reaction mechanisms artificial Diels--Alderases are discussed.
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