Swelling properties of alkali-metal doped polymeric anion-exchange membranes in alcohol media for application in fuel cells
作者： L. Laín , V.M. Barragán
DOI: 10.1016/J.IJHYDENE.2016.05.283
关键词:
摘要: Abstract Swelling properties of four commercial anion-exchange membranes with different structure have been analyzed in several hydro-organic media. With this target, the liquid uptake and surface expansion contact pure liquids, water alcohols (methanol, ethanol 1-propanol), water–alcohol mixtures concentrations experimentally determined presence absence an alkaline medium (LiOH, NaOH KOH concentrations). The alkali-metal doping effect on membrane has also investigated, analyzing influence hydroxide concentration alcohol solution. results show that plays essential role nature media selective membrane. heterogeneous membranes, lower density, higher uptakes dimensional changes than homogeneous regardless conditions.
sci-hub.se 参考文章(33)
Pal M. Sipos, Glenn Hefter, Peter M. May, Viscosities and Densities of Highly Concentrated Aqueous MOH Solutions (M+ = Na+, K+, Li+, Cs+, (CH3)4N+) at 25.0 °C Journal of Chemical & Engineering Data. ,vol. 45, pp. 613- 617 ,(2000) , 10.1021/JE000019H
Jie Cheng, Gaohong He, Fengxiang Zhang, A mini-review on anion exchange membranes for fuel cell applications: Stability issue and addressing strategies International Journal of Hydrogen Energy. ,vol. 40, pp. 7348- 7360 ,(2015) , 10.1016/J.IJHYDENE.2015.04.040
VM Barragán, S Muñoz, None, Influence of a Microwave Irradiation on the Swelling and Permeation Properties of a Nafion Membrane Journal of Membrane and Separation Technology. ,vol. 4, pp. 32- 39 ,(2015)
L. Zeng, T.S. Zhao, L. An, G. Zhao, X.H. Yan, Physicochemical properties of alkaline doped polybenzimidazole membranes for anion exchange membrane fuel cells Journal of Membrane Science. ,vol. 493, pp. 340- 348 ,(2015) , 10.1016/J.MEMSCI.2015.06.013
R.W. Verjulio, J. Santander, N. Sabaté, J.P. Esquivel, N. Torres-Herrero, A. Habrioux, N. Alonso-Vante, Fabrication and evaluation of a passive alkaline membrane micro direct methanol fuel cell International Journal of Hydrogen Energy. ,vol. 39, pp. 5406- 5413 ,(2014) , 10.1016/J.IJHYDENE.2013.12.014
Yukio Mizutani, Structure of ion exchange membranes Journal of Membrane Science. ,vol. 49, pp. 121- 144 ,(1990) , 10.1016/S0376-7388(00)80784-X
F. Karas, J. Hnát, M. Paidar, J. Schauer, K. Bouzek, Determination of the ion-exchange capacity of anion-selective membranes International Journal of Hydrogen Energy. ,vol. 39, pp. 5054- 5062 ,(2014) , 10.1016/J.IJHYDENE.2014.01.074
Xuhai Wang, Joshua P. McClure, Peter S. Fedkiw, Transport properties of proton- and hydroxide-exchange membranes for fuel cells Electrochimica Acta. ,vol. 79, pp. 126- 132 ,(2012) , 10.1016/J.ELECTACTA.2012.06.098
Kyung Won Han, Kwan Ho Ko, Khaldoon Abu-Hakmeh, Chulsung Bae, Young Jun Sohn, Seung Soon Jang, Molecular Dynamics Simulation Study of a Polysulfone-Based Anion Exchange Membrane in Comparison with the Proton Exchange Membrane Journal of Physical Chemistry C. ,vol. 118, pp. 12577- 12587 ,(2014) , 10.1021/JP412473J
O. Souilah, D.E. Akretche, M. Amara, Water reuse of an industrial effluent by means of electrodeionisation Desalination. ,vol. 167, pp. 49- 54 ,(2004) , 10.1016/J.DESAL.2004.06.112