Nickel-catalyzed direct C-H bond sulfenylation of acylhydrazines.
作者： Jun-Ming Li , Yang Yu , Jiang Weng , Gui Lu
DOI: 10.1039/C8OB01481G
关键词:
摘要: A Ni-catalyzed direct C–H bond sulfenylation of acylhydrazines was developed. The reaction used N-(pyridinyl)hydrazine as the bidentate-directing group, which can be smoothly removed through reductive N–N cleavage. This system bear various important functional groups, providing an efficient route for preparation diverse diaryl sulfides.
rsc.org
sci-hub.se 参考文章(76)
Xingwang Zheng, Jinchang Ding, Jiuxi Chen, Wenxiao Gao, Miaochang Liu, Huayue Wu, The coupling of arylboronic acids with nitroarenes catalyzed by rhodium. Organic Letters. ,vol. 13, pp. 1726- 1729 ,(2011) , 10.1021/OL200251X
Monika Mishra, Karishma Tiwari, Punita Mourya, M.M. Singh, Vinod P. Singh, Synthesis, characterization and corrosion inhibition property of nickel(II) and copper(II) complexes with some acylhydrazine Schiff bases Polyhedron. ,vol. 89, pp. 29- 38 ,(2015) , 10.1016/J.POLY.2015.01.003
Ly Dieu Tran, Ilya Popov, Olafs Daugulis, Copper-Promoted Sulfenylation of sp2 C–H Bonds Journal of the American Chemical Society. ,vol. 134, pp. 18237- 18240 ,(2012) , 10.1021/JA3092278
Claudio F. Sturino, Alex G. Fallis, Samarium(II) Iodide Induced Radical Cyclizations of Halo- and Carbonylhydrazones Journal of the American Chemical Society. ,vol. 116, pp. 7447- 7448 ,(1994) , 10.1021/JA00095A074
Manuel A. Fernández-Rodríguez, Qilong Shen, John F. Hartwig, A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols. Journal of the American Chemical Society. ,vol. 128, pp. 2180- 2181 ,(2006) , 10.1021/JA0580340
Hui Ding, Gregory K. Friestad, Trifluoroacetyl-Activated Nitrogen−Nitrogen Bond Cleavage of Hydrazines by Samarium(II) Iodide Organic Letters. ,vol. 6, pp. 637- 640 ,(2004) , 10.1021/OL036480R
Sushilkumar S. Bahekar, Aniket P. Sarkate, Vijay M. Wadhai, Pravin S. Wakte, Devanand B. Shinde, CuI catalyzed CS bond formation by using nitroarenes Catalysis Communications. ,vol. 41, pp. 123- 125 ,(2013) , 10.1016/J.CATCOM.2013.07.019
Chad C. Eichman, James P. Stambuli, Transition metal catalyzed synthesis of aryl sulfides. Molecules. ,vol. 16, pp. 590- 608 ,(2011) , 10.3390/MOLECULES16010590
Sheng-Yi Yan, Yue-Jin Liu, Bin Liu, Yan-Hua Liu, Bing-Feng Shi, Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides. Chemical Communications. ,vol. 51, pp. 4069- 4072 ,(2015) , 10.1039/C4CC10446C
Song Lian, Hua Su, Bao-Xiang Zhao, Wei-Yong Liu, Liang-Wen Zheng, Jun-Ying Miao, Synthesis and discovery of pyrazole-5-carbohydrazide N-glycosides as inducer of autophagy in A549 lung cancer cells Bioorganic & Medicinal Chemistry. ,vol. 17, pp. 7085- 7092 ,(2009) , 10.1016/J.BMC.2009.09.004